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The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand : Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3. / Klementyeva, Svetlana V.; Gritsan, Nina P.; Khusniyarov, Marat M. и др.

в: Chemistry - A European Journal, Том 23, № 6, 26.01.2017, стр. 1278-1290.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Klementyeva, SV, Gritsan, NP, Khusniyarov, MM, Witt, A, Dmitriev, AA, Suturina, EA, Hill, NDD, Roemmele, TL, Gamer, MT, Boeré, RT, Roesky, PW, Zibarev, AV & Konchenko, SN 2017, 'The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3', Chemistry - A European Journal, Том. 23, № 6, стр. 1278-1290. https://doi.org/10.1002/chem.201604340

APA

Klementyeva, S. V., Gritsan, N. P., Khusniyarov, M. M., Witt, A., Dmitriev, A. A., Suturina, E. A., Hill, N. D. D., Roemmele, T. L., Gamer, M. T., Boeré, R. T., Roesky, P. W., Zibarev, A. V., & Konchenko, S. N. (2017). The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3. Chemistry - A European Journal, 23(6), 1278-1290. https://doi.org/10.1002/chem.201604340

Vancouver

Klementyeva SV, Gritsan NP, Khusniyarov MM, Witt A, Dmitriev AA, Suturina EA и др. The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3. Chemistry - A European Journal. 2017 янв. 26;23(6):1278-1290. doi: 10.1002/chem.201604340

Author

Klementyeva, Svetlana V. ; Gritsan, Nina P. ; Khusniyarov, Marat M. и др. / The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand : Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3. в: Chemistry - A European Journal. 2017 ; Том 23, № 6. стр. 1278-1290.

BibTeX

@article{897fcc0b68db45f5bbfe898be6e84589,
title = "The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3",
abstract = "The first lanthanide complexes with a redox-active sulfur diimide ligand, [LnCp*2(Me3SiN=)2S] (Ln=Sm, Eu, Yb; Cp*=η5-C5Me5), are reported. The complexes were synthesized by using [LnCp*2(THF)2] and (Me3SiN=)2S and have been thoroughly characterized by single-crystal X-ray diffraction, EPR spectroscopy, UV/Vis/NIR electronic absorption spectroscopy and SQUID magnetometry. The results, as interpreted by CASSCF/SOC-RASSI calculations providing a non-perturbative treatment of spin-orbit coupling, indicate that these paramagnetic complexes are best described as Ln3+ and [(Me3SiN=)2S]− . adducts. As such, these complexes contain the first isolated and structurally characterized acyclic [(RN=)2S]− . radical anions.",
keywords = "lanthanides, magnetism, quantum chemical calculations, radicals, sulfur diimide, COORDINATION CHEMISTRY, DECAMETHYLYTTERBOCENE COMPLEXES, Z,Z CONFIGURATION, CRYSTAL-STRUCTURE, STRUCTURAL-CHARACTERIZATION, SINGLE-MOLECULE MAGNETS, TRANSITION-METAL, INTERMEDIATE-VALENCE, HETEROCYCLIC RADICAL-ANION, EXCHANGE INTERACTION",
author = "Klementyeva, {Svetlana V.} and Gritsan, {Nina P.} and Khusniyarov, {Marat M.} and Alexander Witt and Dmitriev, {Alexey A.} and Suturina, {Elizaveta A.} and Hill, {Nathan D.D.} and Roemmele, {Tracey L.} and Gamer, {Michael T.} and Boer{\'e}, {Ren{\'e} T.} and Roesky, {Peter W.} and Zibarev, {Andrey V.} and Konchenko, {Sergey N.}",
note = "{\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2017",
month = jan,
day = "26",
doi = "10.1002/chem.201604340",
language = "English",
volume = "23",
pages = "1278--1290",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "6",

}

RIS

TY - JOUR

T1 - The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand

T2 - Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3

AU - Klementyeva, Svetlana V.

AU - Gritsan, Nina P.

AU - Khusniyarov, Marat M.

AU - Witt, Alexander

AU - Dmitriev, Alexey A.

AU - Suturina, Elizaveta A.

AU - Hill, Nathan D.D.

AU - Roemmele, Tracey L.

AU - Gamer, Michael T.

AU - Boeré, René T.

AU - Roesky, Peter W.

AU - Zibarev, Andrey V.

AU - Konchenko, Sergey N.

N1 - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2017/1/26

Y1 - 2017/1/26

N2 - The first lanthanide complexes with a redox-active sulfur diimide ligand, [LnCp*2(Me3SiN=)2S] (Ln=Sm, Eu, Yb; Cp*=η5-C5Me5), are reported. The complexes were synthesized by using [LnCp*2(THF)2] and (Me3SiN=)2S and have been thoroughly characterized by single-crystal X-ray diffraction, EPR spectroscopy, UV/Vis/NIR electronic absorption spectroscopy and SQUID magnetometry. The results, as interpreted by CASSCF/SOC-RASSI calculations providing a non-perturbative treatment of spin-orbit coupling, indicate that these paramagnetic complexes are best described as Ln3+ and [(Me3SiN=)2S]− . adducts. As such, these complexes contain the first isolated and structurally characterized acyclic [(RN=)2S]− . radical anions.

AB - The first lanthanide complexes with a redox-active sulfur diimide ligand, [LnCp*2(Me3SiN=)2S] (Ln=Sm, Eu, Yb; Cp*=η5-C5Me5), are reported. The complexes were synthesized by using [LnCp*2(THF)2] and (Me3SiN=)2S and have been thoroughly characterized by single-crystal X-ray diffraction, EPR spectroscopy, UV/Vis/NIR electronic absorption spectroscopy and SQUID magnetometry. The results, as interpreted by CASSCF/SOC-RASSI calculations providing a non-perturbative treatment of spin-orbit coupling, indicate that these paramagnetic complexes are best described as Ln3+ and [(Me3SiN=)2S]− . adducts. As such, these complexes contain the first isolated and structurally characterized acyclic [(RN=)2S]− . radical anions.

KW - lanthanides

KW - magnetism

KW - quantum chemical calculations

KW - radicals

KW - sulfur diimide

KW - COORDINATION CHEMISTRY

KW - DECAMETHYLYTTERBOCENE COMPLEXES

KW - Z,Z CONFIGURATION

KW - CRYSTAL-STRUCTURE

KW - STRUCTURAL-CHARACTERIZATION

KW - SINGLE-MOLECULE MAGNETS

KW - TRANSITION-METAL

KW - INTERMEDIATE-VALENCE

KW - HETEROCYCLIC RADICAL-ANION

KW - EXCHANGE INTERACTION

UR - http://www.scopus.com/inward/record.url?scp=85006852922&partnerID=8YFLogxK

U2 - 10.1002/chem.201604340

DO - 10.1002/chem.201604340

M3 - Article

C2 - 27783442

AN - SCOPUS:85006852922

VL - 23

SP - 1278

EP - 1290

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 6

ER -

ID: 9052625