Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8. / Ogiwara, Naoki; Kolokolov, Daniil I.; Donoshita, Masaki и др.
в: Chemical Communications, Том 55, № 42, 25.05.2019, стр. 5906-5909.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8
AU - Ogiwara, Naoki
AU - Kolokolov, Daniil I.
AU - Donoshita, Masaki
AU - Kobayashi, Hirokazu
AU - Horike, Satoshi
AU - Stepanov, Alexander G.
AU - Kitagawa, Hiroshi
N1 - Publisher Copyright: © 2019 The Royal Society of Chemistry.
PY - 2019/5/25
Y1 - 2019/5/25
N2 - We investigated the effect of amorphization on the mobility of the 2-methylimidazolate linkers in ZIF-8. Solid-state 2 H NMR studies revealed that amorphization significantly affects the mobility of the linkers, including the rotational angle and speed. Furthermore, a new intermediate librational mode appeared in amorphous ZIF-8.
AB - We investigated the effect of amorphization on the mobility of the 2-methylimidazolate linkers in ZIF-8. Solid-state 2 H NMR studies revealed that amorphization significantly affects the mobility of the linkers, including the rotational angle and speed. Furthermore, a new intermediate librational mode appeared in amorphous ZIF-8.
KW - METAL-ORGANIC FRAMEWORKS
KW - COORDINATION POLYMERS
KW - NMR
KW - DYNAMICS
KW - ROTATION
KW - CRYSTAL
KW - LIQUID
KW - ROTOR
KW - GLASS
UR - http://www.scopus.com/inward/record.url?scp=85065985192&partnerID=8YFLogxK
U2 - 10.1039/c9cc02673h
DO - 10.1039/c9cc02673h
M3 - Article
C2 - 31045195
AN - SCOPUS:85065985192
VL - 55
SP - 5906
EP - 5909
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 42
ER -
ID: 20044377