Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The conductivity and ionic transport of doped bismuth titanate pyrochlore Bi1.6МxTi2O7 − δ (М – Mg, Sc, Cu). / Krasnov, A. G.; Piir, I. V.; Koroleva, M. S. и др.
в: Solid State Ionics, Том 302, 01.04.2017, стр. 118-125.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The conductivity and ionic transport of doped bismuth titanate pyrochlore Bi1.6МxTi2O7 − δ (М – Mg, Sc, Cu)
AU - Krasnov, A. G.
AU - Piir, I. V.
AU - Koroleva, M. S.
AU - Sekushin, N. A.
AU - Ryabkov, Y. I.
AU - Piskaykina, M. M.
AU - Sadykov, V. A.
AU - Sadovskaya, E. M.
AU - Pelipenko, V. V.
AU - Eremeev, N. F.
PY - 2017/4/1
Y1 - 2017/4/1
N2 - Pyrochlores Mg-, Sc-, Cu-doped bismuth titanates have been obtained. The results of X-ray powder diffraction structure refinement and the pycnometric density measurement point to the preference of the dopants distribution in the A-sites of the pyrochlore structure. Electric properties were studied for single phase compounds. The mixed electron-ionic conductivity was indicated in these samples. The high temperature (T > 300 °C) relaxation process was observed in Bi1.6MxTi2O7 − δ at the range of frequency 103–106 Hz. Oxygen mobility and surface reactivity of Bi1.6M0.2Ti2O7 − δ (M – Sc, Mg and Cu) and Bi1.4Mg0.2Ti2O7 − δ samples were studied by using temperature programmed isotope exchange (TPIE) with C18O2 in flow and closed reactors. According to TPIE data the regular lattice oxygen is homogeneous from the point of view of its mobility.
AB - Pyrochlores Mg-, Sc-, Cu-doped bismuth titanates have been obtained. The results of X-ray powder diffraction structure refinement and the pycnometric density measurement point to the preference of the dopants distribution in the A-sites of the pyrochlore structure. Electric properties were studied for single phase compounds. The mixed electron-ionic conductivity was indicated in these samples. The high temperature (T > 300 °C) relaxation process was observed in Bi1.6MxTi2O7 − δ at the range of frequency 103–106 Hz. Oxygen mobility and surface reactivity of Bi1.6M0.2Ti2O7 − δ (M – Sc, Mg and Cu) and Bi1.4Mg0.2Ti2O7 − δ samples were studied by using temperature programmed isotope exchange (TPIE) with C18O2 in flow and closed reactors. According to TPIE data the regular lattice oxygen is homogeneous from the point of view of its mobility.
KW - Bismuth-titanates
KW - Conductivity
KW - Oxygen isotope exchange
KW - Pyrochlore
KW - BI2TI2O7
KW - NEUTRON
KW - TEMPERATURE
KW - ELECTRICAL-PROPERTIES
KW - RELAXATION
KW - DIFFRACTION
UR - http://www.scopus.com/inward/record.url?scp=85009349899&partnerID=8YFLogxK
U2 - 10.1016/j.ssi.2016.12.019
DO - 10.1016/j.ssi.2016.12.019
M3 - Article
AN - SCOPUS:85009349899
VL - 302
SP - 118
EP - 125
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
ER -
ID: 10036623