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The application of novel Ir-NHC polarization transfer complexes by SABRE. / Hadjiali, Sara; Bergmann, Marvin; Kiryutin, Alexey и др.

в: Journal of Chemical Physics, Том 151, № 24, 244201, 28.12.2019.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Hadjiali, S, Bergmann, M, Kiryutin, A, Knecht, S, Sauer, G, Plaumann, M, Limbach, HH, Plenio, H & Buntkowsky, G 2019, 'The application of novel Ir-NHC polarization transfer complexes by SABRE', Journal of Chemical Physics, Том. 151, № 24, 244201. https://doi.org/10.1063/1.5128091

APA

Hadjiali, S., Bergmann, M., Kiryutin, A., Knecht, S., Sauer, G., Plaumann, M., Limbach, H. H., Plenio, H., & Buntkowsky, G. (2019). The application of novel Ir-NHC polarization transfer complexes by SABRE. Journal of Chemical Physics, 151(24), [244201]. https://doi.org/10.1063/1.5128091

Vancouver

Hadjiali S, Bergmann M, Kiryutin A, Knecht S, Sauer G, Plaumann M и др. The application of novel Ir-NHC polarization transfer complexes by SABRE. Journal of Chemical Physics. 2019 дек. 28;151(24):244201. doi: 10.1063/1.5128091

Author

Hadjiali, Sara ; Bergmann, Marvin ; Kiryutin, Alexey и др. / The application of novel Ir-NHC polarization transfer complexes by SABRE. в: Journal of Chemical Physics. 2019 ; Том 151, № 24.

BibTeX

@article{370719679deb4fe8a753cbfc40fa1e52,
title = "The application of novel Ir-NHC polarization transfer complexes by SABRE",
abstract = "In recent years, the hyperpolarization method Signal Amplification By Reversible Exchange (SABRE) has developed into a powerful technique to enhance Nuclear Magnetic Resonance (NMR) signals of organic substrates in solution (mostly via binding to the nitrogen lone pair of N-heterocyclic compounds) by several orders of magnitude. In order to establish the application and development of SABRE as a hyperpolarization method for medical imaging, the separation of the Ir-N-Heterocyclic Carbene (Ir-NHC) complex, which facilitates the hyperpolarization of the substrates in solution, is indispensable. Here, we report for the first time the use of novel Ir-NHC complexes with a polymer unit substitution in the backbone of N-Heterocyclic Carbenes (NHC) for SABRE hyperpolarization, which permits the removal of the complexes from solution after the hyperpolarization of a target substrate has been generated.",
keywords = "HETEROCYCLIC CARBENE COMPLEXES, DYNAMIC NUCLEAR-POLARIZATION, NMR SIGNAL AMPLIFICATION, PARA-HYDROGEN, REVERSIBLE INTERACTIONS, MAGNETIZATION-TRANSFER, SPIN, CATALYSTS, EXCHANGE, HYPERPOLARIZATION",
author = "Sara Hadjiali and Marvin Bergmann and Alexey Kiryutin and Stephan Knecht and Grit Sauer and Markus Plaumann and Limbach, {Hans Heinrich} and Herbert Plenio and Gerd Buntkowsky",
year = "2019",
month = dec,
day = "28",
doi = "10.1063/1.5128091",
language = "English",
volume = "151",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "24",

}

RIS

TY - JOUR

T1 - The application of novel Ir-NHC polarization transfer complexes by SABRE

AU - Hadjiali, Sara

AU - Bergmann, Marvin

AU - Kiryutin, Alexey

AU - Knecht, Stephan

AU - Sauer, Grit

AU - Plaumann, Markus

AU - Limbach, Hans Heinrich

AU - Plenio, Herbert

AU - Buntkowsky, Gerd

PY - 2019/12/28

Y1 - 2019/12/28

N2 - In recent years, the hyperpolarization method Signal Amplification By Reversible Exchange (SABRE) has developed into a powerful technique to enhance Nuclear Magnetic Resonance (NMR) signals of organic substrates in solution (mostly via binding to the nitrogen lone pair of N-heterocyclic compounds) by several orders of magnitude. In order to establish the application and development of SABRE as a hyperpolarization method for medical imaging, the separation of the Ir-N-Heterocyclic Carbene (Ir-NHC) complex, which facilitates the hyperpolarization of the substrates in solution, is indispensable. Here, we report for the first time the use of novel Ir-NHC complexes with a polymer unit substitution in the backbone of N-Heterocyclic Carbenes (NHC) for SABRE hyperpolarization, which permits the removal of the complexes from solution after the hyperpolarization of a target substrate has been generated.

AB - In recent years, the hyperpolarization method Signal Amplification By Reversible Exchange (SABRE) has developed into a powerful technique to enhance Nuclear Magnetic Resonance (NMR) signals of organic substrates in solution (mostly via binding to the nitrogen lone pair of N-heterocyclic compounds) by several orders of magnitude. In order to establish the application and development of SABRE as a hyperpolarization method for medical imaging, the separation of the Ir-N-Heterocyclic Carbene (Ir-NHC) complex, which facilitates the hyperpolarization of the substrates in solution, is indispensable. Here, we report for the first time the use of novel Ir-NHC complexes with a polymer unit substitution in the backbone of N-Heterocyclic Carbenes (NHC) for SABRE hyperpolarization, which permits the removal of the complexes from solution after the hyperpolarization of a target substrate has been generated.

KW - HETEROCYCLIC CARBENE COMPLEXES

KW - DYNAMIC NUCLEAR-POLARIZATION

KW - NMR SIGNAL AMPLIFICATION

KW - PARA-HYDROGEN

KW - REVERSIBLE INTERACTIONS

KW - MAGNETIZATION-TRANSFER

KW - SPIN

KW - CATALYSTS

KW - EXCHANGE

KW - HYPERPOLARIZATION

UR - http://www.scopus.com/inward/record.url?scp=85077315579&partnerID=8YFLogxK

U2 - 10.1063/1.5128091

DO - 10.1063/1.5128091

M3 - Article

C2 - 31893872

AN - SCOPUS:85077315579

VL - 151

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 24

M1 - 244201

ER -

ID: 23053478