Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine : Syntheses and Crystal Structures. / Usoltsev, A. N.; Adonin, S. A.; Abramov, P. A. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 44, № 12, 01.12.2018, стр. 772-778.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine
T2 - Syntheses and Crystal Structures
AU - Usoltsev, A. N.
AU - Adonin, S. A.
AU - Abramov, P. A.
AU - Sokolov, M. N.
AU - Fedin, V. P.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.
AB - Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.
KW - bismuth
KW - halide complexes
KW - supramolecular contacts
KW - tetramethylpyrazine
KW - X-ray diffraction analysis
KW - COMPLEXES
KW - OPTICAL-PROPERTIES
KW - SOLID-STATE
KW - BISMUTH IODIDE
UR - http://www.scopus.com/inward/record.url?scp=85060273284&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/e530513e-d945-3255-b769-12428635e827/
U2 - 10.1134/S1070328418120102
DO - 10.1134/S1070328418120102
M3 - Article
AN - SCOPUS:85060273284
VL - 44
SP - 772
EP - 778
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 12
ER -
ID: 18290415