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Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8. / Park, S. J.; Pomelova, T. A.; Kuratieva, N. V. и др.

в: Journal of Structural Chemistry, Том 67, № 7, 30.07.2026, стр. 1516-1525.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Park SJ, Pomelova TA, Kuratieva NV, Filatova IY, Naumov NG. Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8. Journal of Structural Chemistry. 2026 июль 30;67(7):1516-1525. doi: 10.1134/S0022476626070085

Author

Park, S. J. ; Pomelova, T. A. ; Kuratieva, N. V. и др. / Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8. в: Journal of Structural Chemistry. 2026 ; Том 67, № 7. стр. 1516-1525.

BibTeX

@article{ee882d7491d044668d7b9259a5e08401,
title = "Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8",
abstract = "The Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8 layered compounds are prepared for the first time by a reaction of the corresponding lanthanide sulfides with zinc sulfide, rubidium polysulfide, using RbCl as a flux. The synthesized compounds crystallize in the monoclinic space group C2/m. Their crystal structure can be described as a combination of motifs characteristic of KZrCuS3 and α-NaFeO2 structure types. The optical band gaps determined by the Kubelka–Munk method are 1.90 eV (Eu), 3.54 eV (Gd), 3.55 eV (Tb), and 3.42 eV (Ho).",
keywords = "crystal structure, lanthanides, layered compounds, optical properties, quaternary sulfides, лантаноиды, четверные сульфиды, кристаллическая структура, слоистые соединения, оптические свойства",
author = "Park, {S. J.} and Pomelova, {T. A.} and Kuratieva, {N. V.} and Filatova, {I. Y.} and Naumov, {N. G.}",
note = "Park, S.J., Pomelova, T.A., Kuratieva, N.V. et al. Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8. J Struct Chem 67, 1516–1525 (2026). https://doi.org/10.1134/S0022476626070085 This work was funded by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700315-2). ",
year = "2026",
month = jul,
day = "30",
doi = "10.1134/S0022476626070085",
language = "English",
volume = "67",
pages = "1516--1525",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "7",

}

RIS

TY - JOUR

T1 - Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8

AU - Park, S. J.

AU - Pomelova, T. A.

AU - Kuratieva, N. V.

AU - Filatova, I. Y.

AU - Naumov, N. G.

N1 - Park, S.J., Pomelova, T.A., Kuratieva, N.V. et al. Synthesis, Structural Model, and Optical Properties of Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8. J Struct Chem 67, 1516–1525 (2026). https://doi.org/10.1134/S0022476626070085 This work was funded by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700315-2).

PY - 2026/7/30

Y1 - 2026/7/30

N2 - The Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8 layered compounds are prepared for the first time by a reaction of the corresponding lanthanide sulfides with zinc sulfide, rubidium polysulfide, using RbCl as a flux. The synthesized compounds crystallize in the monoclinic space group C2/m. Their crystal structure can be described as a combination of motifs characteristic of KZrCuS3 and α-NaFeO2 structure types. The optical band gaps determined by the Kubelka–Munk method are 1.90 eV (Eu), 3.54 eV (Gd), 3.55 eV (Tb), and 3.42 eV (Ho).

AB - The Rb3Ln3Zn2S8 (Ln = Eu, Gd, Ho) and Cs0.88Rb2.12Tb3Zn2S8 layered compounds are prepared for the first time by a reaction of the corresponding lanthanide sulfides with zinc sulfide, rubidium polysulfide, using RbCl as a flux. The synthesized compounds crystallize in the monoclinic space group C2/m. Their crystal structure can be described as a combination of motifs characteristic of KZrCuS3 and α-NaFeO2 structure types. The optical band gaps determined by the Kubelka–Munk method are 1.90 eV (Eu), 3.54 eV (Gd), 3.55 eV (Tb), and 3.42 eV (Ho).

KW - crystal structure

KW - lanthanides

KW - layered compounds

KW - optical properties

KW - quaternary sulfides

KW - лантаноиды

KW - четверные сульфиды

KW - кристаллическая структура

KW - слоистые соединения

KW - оптические свойства

UR - https://www.mendeley.com/catalogue/3a6c8876-febb-3f6b-bbbb-64806fad6c5e/

UR - https://www.scopus.com/pages/publications/105046332719

U2 - 10.1134/S0022476626070085

DO - 10.1134/S0022476626070085

M3 - Article

VL - 67

SP - 1516

EP - 1525

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 83184493