Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis, morphology and electrochemical properties of spherulite titania nanocrystals. / Popkov, Vadim I.; Bachina, Anastasia K.; Valeeva, Albina A. и др.
в: Ceramics International, Том 46, № 15, 15.10.2020, стр. 24483-24487.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Synthesis, morphology and electrochemical properties of spherulite titania nanocrystals
AU - Popkov, Vadim I.
AU - Bachina, Anastasia K.
AU - Valeeva, Albina A.
AU - Lobinsky, Artem A.
AU - Gerasimov, Evgeny Y.
AU - Rempel, Andrey A.
PY - 2020/10/15
Y1 - 2020/10/15
N2 - A new approach to hydrothermally synthesize nanocrystalline titanium dioxide with a rutile structure and spherulite-like morphology from titanyl citrate is described herein. It was found that titanium dioxide formed as a result of titanyl citrate thermolysis with the following products: rutile nanocrystals, itaconic acid, and carbon dioxide. Rutile nanocrystals were rod-shaped and oriented in the (101) crystallographic direction. The position of the rutile nanocrystals in the spherulites and pores between the nanocrystals lead to high electrocatalytic activity for the oxygen evolution reaction in alkaline aqueous solutions. The process is characterized by a Tafel slope of 49 mV/dec.
AB - A new approach to hydrothermally synthesize nanocrystalline titanium dioxide with a rutile structure and spherulite-like morphology from titanyl citrate is described herein. It was found that titanium dioxide formed as a result of titanyl citrate thermolysis with the following products: rutile nanocrystals, itaconic acid, and carbon dioxide. Rutile nanocrystals were rod-shaped and oriented in the (101) crystallographic direction. The position of the rutile nanocrystals in the spherulites and pores between the nanocrystals lead to high electrocatalytic activity for the oxygen evolution reaction in alkaline aqueous solutions. The process is characterized by a Tafel slope of 49 mV/dec.
KW - Electrocatalysis
KW - Hydrothermal synthesis
KW - Rutile
KW - Spherulites
KW - Titania
UR - http://www.scopus.com/inward/record.url?scp=85087680228&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2020.06.233
DO - 10.1016/j.ceramint.2020.06.233
M3 - Article
AN - SCOPUS:85087680228
VL - 46
SP - 24483
EP - 24487
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 15
ER -
ID: 24767210