Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

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Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer. / Koltunova, T. K.; Samsonenko, D. G.; Rakhmanova, M. I. и др.

в: Russian Chemical Bulletin, Том 64, № 12, 01.12.2015, стр. 2903-2907.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{0aa14bcfbb9441dd891aef716447c48f,

title = "Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer",

abstract = "A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.",

keywords = "cage structures, coordination polymers, lithium(I) complexes, luminescence, X-ray crystallography",

author = "Koltunova, {T. K.} and Samsonenko, {D. G.} and Rakhmanova, {M. I.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2015",

month = dec,

day = "1",

doi = "10.1007/s11172-015-1245-3",

language = "English",

volume = "64",

pages = "2903--2907",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "12",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

AU - Koltunova, T. K.

AU - Samsonenko, D. G.

AU - Rakhmanova, M. I.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

AB - A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

KW - cage structures

KW - coordination polymers

KW - lithium(I) complexes

KW - luminescence

KW - X-ray crystallography

UR - http://www.scopus.com/inward/record.url?scp=84988349930&partnerID=8YFLogxK

U2 - 10.1007/s11172-015-1245-3

DO - 10.1007/s11172-015-1245-3

M3 - Article

AN - SCOPUS:84988349930

VL - 64

SP - 2903

EP - 2907

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

ER -

ID: 25418759