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Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety. / Kokina, T. E.; Glinskaya, L. A.; Piryazev, D. A. и др.

в: Russian Chemical Bulletin, Том 67, № 7, 01.07.2018, стр. 1251-1260.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kokina, TE, Glinskaya, LA, Piryazev, DA, Baranov, AY, Agafontsev, AM, Eremina, YA, Vorontsova, EV, Bogomyakov, AS, Naumov, DY, Tkachev, AV & Larionov, SV 2018, 'Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety', Russian Chemical Bulletin, Том. 67, № 7, стр. 1251-1260. https://doi.org/10.1007/s11172-018-2209-1

APA

Kokina, T. E., Glinskaya, L. A., Piryazev, D. A., Baranov, A. Y., Agafontsev, A. M., Eremina, Y. A., Vorontsova, E. V., Bogomyakov, A. S., Naumov, D. Y., Tkachev, A. V., & Larionov, S. V. (2018). Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety. Russian Chemical Bulletin, 67(7), 1251-1260. https://doi.org/10.1007/s11172-018-2209-1

Vancouver

Kokina TE, Glinskaya LA, Piryazev DA, Baranov AY, Agafontsev AM, Eremina YA и др. Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety. Russian Chemical Bulletin. 2018 июль 1;67(7):1251-1260. doi: 10.1007/s11172-018-2209-1

Author

Kokina, T. E. ; Glinskaya, L. A. ; Piryazev, D. A. и др. / Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety. в: Russian Chemical Bulletin. 2018 ; Том 67, № 7. стр. 1251-1260.

BibTeX

@article{3a3ec6d37df64648bffdb65ee6692899,
title = "Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety",
abstract = "The complex salt {[CuL2][Cu4I6]•MeCN}n (1) and the compound [Cu4L3I4]•3 MeCN (2) (L is a chiral ligand bearing a natural monoterpene (+)-3-carene moiety) were synthesized. The crystal structures of compounds 1 and 2 were determined by X-ray diffraction. The structure of compound 1 consists of complex cations [CuL2]2+ (N3O2 polyhedron is a trigonal bipyramid) and CuI coordination polymers (CuI4 polyhedron is a tetrahedron) as anions. The experimental magnetic moment μeff at 300 K is 1.90 μB, which is consistent with the X-ray diffraction data and the assumption that compound 1 is mixed-valence. The structure of compound 2 comprises a tetranuclear CuI complex, in which three Cu atoms are coordinated by two N atoms of the ligand L and two I atoms, and the fourth Cu atom is coordinated by four I atoms (coordination polyhedra are distorted tetrahedra). Compounds L and 2 were found to influence the viability of human laryngeal carcinoma cells (Hep2). The IC50 value for complex 2 (13.0±1.7 μM) is substantially smaller than IC50 for compound L (30.5±0.5 μM).",
keywords = "chiral ligand, coordination framework, copper(I,II) complexes, crystal structure, cytotoxicity, iodide complex, terpenes, copper(I, II) complexes, COPPER-COMPLEXES, PHOTOLUMINESCENCE, CRYSTAL-STRUCTURE, PYRIDINE, ZINC(II), COORDINATION-COMPOUNDS, PYRAZOLYLQUINOLINE, METAL-COMPLEXES",
author = "Kokina, {T. E.} and Glinskaya, {L. A.} and Piryazev, {D. A.} and Baranov, {A. Yu} and Agafontsev, {A. M.} and Eremina, {Yu A.} and Vorontsova, {E. V.} and Bogomyakov, {A. S.} and Naumov, {D. Yu} and Tkachev, {A. V.} and Larionov, {S. V.}",
note = "Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",
year = "2018",
month = jul,
day = "1",
doi = "10.1007/s11172-018-2209-1",
language = "English",
volume = "67",
pages = "1251--1260",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "7",

}

RIS

TY - JOUR

T1 - Synthesis and structures of CuI,II complexes with a 2,2´-bipyridine derivative bearing a (+)-3-carene moiety

AU - Kokina, T. E.

AU - Glinskaya, L. A.

AU - Piryazev, D. A.

AU - Baranov, A. Yu

AU - Agafontsev, A. M.

AU - Eremina, Yu A.

AU - Vorontsova, E. V.

AU - Bogomyakov, A. S.

AU - Naumov, D. Yu

AU - Tkachev, A. V.

AU - Larionov, S. V.

N1 - Publisher Copyright: © 2018, Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The complex salt {[CuL2][Cu4I6]•MeCN}n (1) and the compound [Cu4L3I4]•3 MeCN (2) (L is a chiral ligand bearing a natural monoterpene (+)-3-carene moiety) were synthesized. The crystal structures of compounds 1 and 2 were determined by X-ray diffraction. The structure of compound 1 consists of complex cations [CuL2]2+ (N3O2 polyhedron is a trigonal bipyramid) and CuI coordination polymers (CuI4 polyhedron is a tetrahedron) as anions. The experimental magnetic moment μeff at 300 K is 1.90 μB, which is consistent with the X-ray diffraction data and the assumption that compound 1 is mixed-valence. The structure of compound 2 comprises a tetranuclear CuI complex, in which three Cu atoms are coordinated by two N atoms of the ligand L and two I atoms, and the fourth Cu atom is coordinated by four I atoms (coordination polyhedra are distorted tetrahedra). Compounds L and 2 were found to influence the viability of human laryngeal carcinoma cells (Hep2). The IC50 value for complex 2 (13.0±1.7 μM) is substantially smaller than IC50 for compound L (30.5±0.5 μM).

AB - The complex salt {[CuL2][Cu4I6]•MeCN}n (1) and the compound [Cu4L3I4]•3 MeCN (2) (L is a chiral ligand bearing a natural monoterpene (+)-3-carene moiety) were synthesized. The crystal structures of compounds 1 and 2 were determined by X-ray diffraction. The structure of compound 1 consists of complex cations [CuL2]2+ (N3O2 polyhedron is a trigonal bipyramid) and CuI coordination polymers (CuI4 polyhedron is a tetrahedron) as anions. The experimental magnetic moment μeff at 300 K is 1.90 μB, which is consistent with the X-ray diffraction data and the assumption that compound 1 is mixed-valence. The structure of compound 2 comprises a tetranuclear CuI complex, in which three Cu atoms are coordinated by two N atoms of the ligand L and two I atoms, and the fourth Cu atom is coordinated by four I atoms (coordination polyhedra are distorted tetrahedra). Compounds L and 2 were found to influence the viability of human laryngeal carcinoma cells (Hep2). The IC50 value for complex 2 (13.0±1.7 μM) is substantially smaller than IC50 for compound L (30.5±0.5 μM).

KW - chiral ligand

KW - coordination framework

KW - copper(I,II) complexes

KW - crystal structure

KW - cytotoxicity

KW - iodide complex

KW - terpenes

KW - copper(I, II) complexes

KW - COPPER-COMPLEXES

KW - PHOTOLUMINESCENCE

KW - CRYSTAL-STRUCTURE

KW - PYRIDINE

KW - ZINC(II)

KW - COORDINATION-COMPOUNDS

KW - PYRAZOLYLQUINOLINE

KW - METAL-COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85054165659&partnerID=8YFLogxK

U2 - 10.1007/s11172-018-2209-1

DO - 10.1007/s11172-018-2209-1

M3 - Article

AN - SCOPUS:85054165659

VL - 67

SP - 1251

EP - 1260

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7

ER -

ID: 16948073