Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis and structure of two novel metal-organic frameworks based on cluster anions [Re6Se8(CN)(6)](4-), cations Tb3+ and isonicotinate anions. / Litvinova, Yu M.; Gayfulin, Ya M.; Samsonenko, D. G. и др.
в: Journal of Structural Chemistry, Том 61, № 10, 10.2020, стр. 1630-1638.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and structure of two novel metal-organic frameworks based on cluster anions [Re6Se8(CN)(6)](4-), cations Tb3+ and isonicotinate anions
AU - Litvinova, Yu M.
AU - Gayfulin, Ya M.
AU - Samsonenko, D. G.
AU - Dorovatovsky, P.
AU - Lazarenko, V. A.
AU - Mironov, Yu
N1 - Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2020/10
Y1 - 2020/10
N2 - The interaction of cluster anions [Re 6Se 8(CN) 6] 4– with cations Tb 3+ in the presence of 4-cyanopyridine in aqueous solution is studied. Two novel framework compounds (K[{Tb 3(H 2O) 2}(ina) 2}{Re 6Se 8(CN) 6} 2]·7H 2O (1) and [{Tb 4(OH) 4(μ-ina) 2(ina) 2(H 2O) 4}{Re 6Se 8(CN) 6}]·7.5H 2O (2) where ina = isonicotinic acid anion) are prepared by the solvothermal synthesis as a result of 4-cyanopyridine hydrolysis to produce isonicotinic acid and subsequent self-assembly in solution with cations Tb 3+ and a presynthesized cluster anion [Re 6Se 8(CN) 6] 4–.
AB - The interaction of cluster anions [Re 6Se 8(CN) 6] 4– with cations Tb 3+ in the presence of 4-cyanopyridine in aqueous solution is studied. Two novel framework compounds (K[{Tb 3(H 2O) 2}(ina) 2}{Re 6Se 8(CN) 6} 2]·7H 2O (1) and [{Tb 4(OH) 4(μ-ina) 2(ina) 2(H 2O) 4}{Re 6Se 8(CN) 6}]·7.5H 2O (2) where ina = isonicotinic acid anion) are prepared by the solvothermal synthesis as a result of 4-cyanopyridine hydrolysis to produce isonicotinic acid and subsequent self-assembly in solution with cations Tb 3+ and a presynthesized cluster anion [Re 6Se 8(CN) 6] 4–.
KW - rhenium
KW - cluster
KW - lanthanides
KW - crystal structure
KW - coordination polymers
KW - COORDINATION POLYMERS
KW - HYDROTHERMAL SYNTHESIS
KW - CRYSTAL-STRUCTURE
KW - LANTHANIDE
KW - COMPLEXES
KW - LN
KW - MOLYBDENUM
KW - REDOX
UR - http://www.scopus.com/inward/record.url?scp=85106784940&partnerID=8YFLogxK
U2 - 10.1134/S0022476620100169
DO - 10.1134/S0022476620100169
M3 - Article
VL - 61
SP - 1630
EP - 1638
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 10
ER -
ID: 27360183