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Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes. / Bashirov, D. A.; Lashchenko, D. I.; Sukhikh, T. S. и др.

в: Journal of Structural Chemistry, Том 63, № 12, 01.12.2022, стр. 2037-2044.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bashirov, DA, Lashchenko, DI, Sukhikh, TS & Konchenko, SN 2022, 'Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes', Journal of Structural Chemistry, Том. 63, № 12, стр. 2037-2044. https://doi.org/10.1134/S0022476622120150

APA

Bashirov, D. A., Lashchenko, D. I., Sukhikh, T. S., & Konchenko, S. N. (2022). Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes. Journal of Structural Chemistry, 63(12), 2037-2044. https://doi.org/10.1134/S0022476622120150

Vancouver

Bashirov DA, Lashchenko DI, Sukhikh TS, Konchenko SN. Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes. Journal of Structural Chemistry. 2022 дек. 1;63(12):2037-2044. doi: 10.1134/S0022476622120150

Author

Bashirov, D. A. ; Lashchenko, D. I. ; Sukhikh, T. S. и др. / Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes. в: Journal of Structural Chemistry. 2022 ; Том 63, № 12. стр. 2037-2044.

BibTeX

@article{66a3b3acf3b741a392c69e11311be8bc,
title = "Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes",
abstract = "New silanediamide complexes of divalent lanthanides with different metal-to-ligand ratios are synthesized: K[K(THF)][Yb(Me2Si(NMes)2)2] (1) and [Eu2(Me2Si(NMes)2)2(THF)3] (2) (Mes = 2,4,6-(CH3)C6H2 == mesityl). The compounds are isolated as crystalline phases 1 and 2·C7H8 and characterized by single crystal X-ray diffraction. Compound 1 is an ate complex in which two silanediamide ligands are coordinated to Yb by nitrogen atoms in a chelate manner, and the potassium ions are linked with aromatic rings of mesityl substituents. In binuclear complex 2, two coordination types of the silanediamide ligand are observed: μ-κ1N,κ2N and μ-κ2N,κ2N.",
keywords = "coordination compounds, crystal structure, europium, lanthanides, silanediamides, synthesis, ytterbium",
author = "Bashirov, {D. A.} and Lashchenko, {D. I.} and Sukhikh, {T. S.} and Konchenko, {S. N.}",
note = "FUNDING: The work was supported by the Russian Science Foundation (grant No. 21-13-00287).",
year = "2022",
month = dec,
day = "1",
doi = "10.1134/S0022476622120150",
language = "English",
volume = "63",
pages = "2037--2044",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Synthesis and structure of Ln(II) (Ln = Eu, Yb) silanediamide complexes

AU - Bashirov, D. A.

AU - Lashchenko, D. I.

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

N1 - FUNDING: The work was supported by the Russian Science Foundation (grant No. 21-13-00287).

PY - 2022/12/1

Y1 - 2022/12/1

N2 - New silanediamide complexes of divalent lanthanides with different metal-to-ligand ratios are synthesized: K[K(THF)][Yb(Me2Si(NMes)2)2] (1) and [Eu2(Me2Si(NMes)2)2(THF)3] (2) (Mes = 2,4,6-(CH3)C6H2 == mesityl). The compounds are isolated as crystalline phases 1 and 2·C7H8 and characterized by single crystal X-ray diffraction. Compound 1 is an ate complex in which two silanediamide ligands are coordinated to Yb by nitrogen atoms in a chelate manner, and the potassium ions are linked with aromatic rings of mesityl substituents. In binuclear complex 2, two coordination types of the silanediamide ligand are observed: μ-κ1N,κ2N and μ-κ2N,κ2N.

AB - New silanediamide complexes of divalent lanthanides with different metal-to-ligand ratios are synthesized: K[K(THF)][Yb(Me2Si(NMes)2)2] (1) and [Eu2(Me2Si(NMes)2)2(THF)3] (2) (Mes = 2,4,6-(CH3)C6H2 == mesityl). The compounds are isolated as crystalline phases 1 and 2·C7H8 and characterized by single crystal X-ray diffraction. Compound 1 is an ate complex in which two silanediamide ligands are coordinated to Yb by nitrogen atoms in a chelate manner, and the potassium ions are linked with aromatic rings of mesityl substituents. In binuclear complex 2, two coordination types of the silanediamide ligand are observed: μ-κ1N,κ2N and μ-κ2N,κ2N.

KW - coordination compounds

KW - crystal structure

KW - europium

KW - lanthanides

KW - silanediamides

KW - synthesis

KW - ytterbium

UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85145386282&partnerID=40&md5=f9e4553c8908876bc74b474b274557e6

UR - https://www.mendeley.com/catalogue/df3a0253-2c49-3682-9b21-67118c6e0726/

U2 - 10.1134/S0022476622120150

DO - 10.1134/S0022476622120150

M3 - Article

VL - 63

SP - 2037

EP - 2044

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 44621945