Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis and Growth of Rare Earth Borates NaSrR(BO3)2(R = Ho-Lu, Y, Sc). / Kuznetsov, Artem B.; Kokh, Konstantin A.; Sagatov, Nursultan и др.
в: Inorganic Chemistry, Том 61, № 19, 16.05.2022, стр. 7497–7505.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and Growth of Rare Earth Borates NaSrR(BO3)2(R = Ho-Lu, Y, Sc)
AU - Kuznetsov, Artem B.
AU - Kokh, Konstantin A.
AU - Sagatov, Nursultan
AU - Gavryushkin, Pavel N.
AU - Molokeev, Maksim S.
AU - Svetlichnyi, Valery A.
AU - Lapin, Ivan N.
AU - Kononova, Nadezda G.
AU - Shevchenko, Vyacheslav S.
AU - Bolatov, Asset
AU - Uralbekov, Bolat
AU - Goreiavcheva, Anastasia A.
AU - Kokh, Alexander E.
N1 - Funding Information: This work was supported by Grant GF MES RK “Crystallochemical design of the new alkali and rare earth-based borate phosphors”, Grant IRN AP08855427, and the state assigned project of IGM SB RAS. Publisher Copyright: © 2022 American Chemical Society.
PY - 2022/5/16
Y1 - 2022/5/16
N2 - NaSrR(BO3)2 (R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+ and Na+ atoms while RO6 polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2 and NaSrYb(BO3)2 by the top seeded solution growth method with Na2O-B2O3-NaF flux.
AB - NaSrR(BO3)2 (R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+ and Na+ atoms while RO6 polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2 and NaSrYb(BO3)2 by the top seeded solution growth method with Na2O-B2O3-NaF flux.
UR - http://www.scopus.com/inward/record.url?scp=85130026665&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/edf6448f-3967-35d7-8521-a2e794a219d6/
U2 - 10.1021/acs.inorgchem.2c00596
DO - 10.1021/acs.inorgchem.2c00596
M3 - Article
C2 - 35503917
AN - SCOPUS:85130026665
VL - 61
SP - 7497
EP - 7505
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 19
ER -
ID: 36124008