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Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH. / Cheplakova, A. M.; Samsonenko, D. G.; Fedin, V. P.

в: Journal of Structural Chemistry, Том 60, № 2, 01.02.2019, стр. 289-293.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Cheplakova, AM, Samsonenko, DG & Fedin, VP 2019, 'Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH', Journal of Structural Chemistry, Том. 60, № 2, стр. 289-293. https://doi.org/10.1134/S002247661902015X

APA

Cheplakova, A. M., Samsonenko, D. G., & Fedin, V. P. (2019). Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH. Journal of Structural Chemistry, 60(2), 289-293. https://doi.org/10.1134/S002247661902015X

Vancouver

Cheplakova AM, Samsonenko DG, Fedin VP. Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH. Journal of Structural Chemistry. 2019 февр. 1;60(2):289-293. doi: 10.1134/S002247661902015X

Author

Cheplakova, A. M. ; Samsonenko, D. G. ; Fedin, V. P. / Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH. в: Journal of Structural Chemistry. 2019 ; Том 60, № 2. стр. 289-293.

BibTeX

@article{5362b7838abc4f379a6bc6a93ea83a91,
title = "Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH",
abstract = " The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ]·2HOCH 2 CH 2 OH (tFBDC 2− = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC 2− anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol. ",
keywords = "crystal structure, metal-organic coordination polymer, scandium complexes, tetrafluoroterephthalic acid, FRAMEWORKS",
author = "Cheplakova, {A. M.} and Samsonenko, {D. G.} and Fedin, {V. P.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1134/S002247661902015X",
language = "English",
volume = "60",
pages = "289--293",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Synthesis and Crystal Structure of Coordination Polymer [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ] · 2HOCH 2 CH 2 OH

AU - Cheplakova, A. M.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ]·2HOCH 2 CH 2 OH (tFBDC 2− = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC 2− anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol.

AB - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc 2 (HOCH 2 CH 2 OH) 4 (tFBDC) 3 ]·2HOCH 2 CH 2 OH (tFBDC 2− = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC 2− anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol.

KW - crystal structure

KW - metal-organic coordination polymer

KW - scandium complexes

KW - tetrafluoroterephthalic acid

KW - FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85065411168&partnerID=8YFLogxK

U2 - 10.1134/S002247661902015X

DO - 10.1134/S002247661902015X

M3 - Article

AN - SCOPUS:85065411168

VL - 60

SP - 289

EP - 293

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 20051556