Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

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Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate. / Gusarov, V. S.; Cheplakova, A. M.; Samsonenko, D. G. и др.

в: Russian Journal of Inorganic Chemistry, Том 66, № 9, 7, 09.2021, стр. 1374-1379.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{a7da73d0c1bb42cca2242707b0f56431,

title = "Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate",

abstract = "The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.",

keywords = "cadmium complexes, crystal structure, metal-organic coordination polymer, octafluorobiphenyl-4,4'-dicarboxylic acid",

author = "Gusarov, {V. S.} and Cheplakova, {A. M.} and Samsonenko, {D. G.} and Vinogradov, {A. S.} and Fedin, {V. P.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research and the Government of the Novosibirsk Region, project no. 20-43-540004. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = sep,

doi = "10.1134/S0036023621090035",

language = "English",

volume = "66",

pages = "1374--1379",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "9",

}

RIS

TY - JOUR

T1 - Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

AU - Gusarov, V. S.

AU - Cheplakova, A. M.

AU - Samsonenko, D. G.

AU - Vinogradov, A. S.

AU - Fedin, V. P.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research and the Government of the Novosibirsk Region, project no. 20-43-540004. Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/9

Y1 - 2021/9

N2 - The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.

AB - The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.

KW - cadmium complexes

KW - crystal structure

KW - metal-organic coordination polymer

KW - octafluorobiphenyl-4,4'-dicarboxylic acid

UR - http://www.scopus.com/inward/record.url?scp=85115202148&partnerID=8YFLogxK

UR - https://www.elibrary.ru/item.asp?id=47046775

U2 - 10.1134/S0036023621090035

DO - 10.1134/S0036023621090035

M3 - Article

AN - SCOPUS:85115202148

VL - 66

SP - 1374

EP - 1379

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 9

M1 - 7

ER -

ID: 34257150