TY - JOUR

T1 - Synergistic effect of combination of surfactant and oxide powder on enhancement of gas hydrates nucleation

AU - Nesterov, Anatoliy N.

AU - Reshetnikov, Aleksey M.

AU - Manakov, Andrey Yu

AU - Adamova, Tatyana P.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - In the present work we studied the induction periods of hydrate formation of natural gas in pure water, aqueous solutions of surfactants, and in the presence of surfactant together with aluminum oxide nanopowder, the activity of which as hydrate formation inducer was studied previously. Sodium dodecyl sulfate (SDS) or neonol AF-9-12 were used as the surfactants. It was demonstrated that the addition of either surfactants or aluminum oxide powder under our experimental conditions causes a decrease in the induction period of hydrate formation from ∼105 min for pure water to 30–35 min for water with additives. In the case of the simultaneous presence of surfactants and aluminum oxide powder in the system, induction period decreased to ∼20 min. So, the synergistic effect of the combination of surfactant and oxide powder on gas hydrate nucleation was demonstrated. Possible reasons of this effect have been discussed.

AB - In the present work we studied the induction periods of hydrate formation of natural gas in pure water, aqueous solutions of surfactants, and in the presence of surfactant together with aluminum oxide nanopowder, the activity of which as hydrate formation inducer was studied previously. Sodium dodecyl sulfate (SDS) or neonol AF-9-12 were used as the surfactants. It was demonstrated that the addition of either surfactants or aluminum oxide powder under our experimental conditions causes a decrease in the induction period of hydrate formation from ∼105 min for pure water to 30–35 min for water with additives. In the case of the simultaneous presence of surfactants and aluminum oxide powder in the system, induction period decreased to ∼20 min. So, the synergistic effect of the combination of surfactant and oxide powder on gas hydrate nucleation was demonstrated. Possible reasons of this effect have been discussed.

KW - Gas hydrate

KW - Hydrate formation

KW - Induction period

KW - Nanopowder

KW - Nucleation

KW - Surfactant

KW - ICE NUCLEATION

KW - SILVER NANOPARTICLES

KW - NATURAL-GAS

KW - PROBABILITY-DISTRIBUTIONS

KW - SODIUM DODECYL-SULFATE

KW - KINETICS

KW - METHANE HYDRATE

KW - SEPARATION

KW - MOLECULAR-DYNAMICS SIMULATIONS

KW - WATER

UR - http://www.scopus.com/inward/record.url?scp=85022092633&partnerID=8YFLogxK

U2 - 10.1016/j.jechem.2017.04.001

DO - 10.1016/j.jechem.2017.04.001

M3 - Article

AN - SCOPUS:85022092633

VL - 26

SP - 808

EP - 814

JO - Journal of Energy Chemistry

JF - Journal of Energy Chemistry

SN - 2095-4956

IS - 4

ER -