Standard

Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties. / Apartsin, Evgeny; Caminade, Anne Marie.

в: Chemistry - A European Journal, Том 27, № 72, 23.12.2021, стр. 17976-17998.

Результаты исследований: Научные публикации в периодических изданияхобзорная статьяРецензирование

Harvard

Apartsin, E & Caminade, AM 2021, 'Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties', Chemistry - A European Journal, Том. 27, № 72, стр. 17976-17998. https://doi.org/10.1002/chem.202102589

APA

Apartsin, E., & Caminade, A. M. (2021). Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties. Chemistry - A European Journal, 27(72), 17976-17998. https://doi.org/10.1002/chem.202102589

Vancouver

Apartsin E, Caminade AM. Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties. Chemistry - A European Journal. 2021 дек. 23;27(72):17976-17998. Epub 2021 окт. 29. doi: 10.1002/chem.202102589

Author

Apartsin, Evgeny ; Caminade, Anne Marie. / Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties. в: Chemistry - A European Journal. 2021 ; Том 27, № 72. стр. 17976-17998.

BibTeX

@article{2b8eaa7ed47142978c00a9820877c70b,
title = "Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties",
abstract = "This review presents precisely defined amphiphilic dendrons, their self-association properties, and their different uses. Dendrons, also named dendritic wedges, are composed of a core having two different types of functions, of which one type is used for growing or grafting branched arms, generally multiplied by 2 at each layer by using 1→2 branching motifs. A large diversity of structures has been already synthesized. In practically all cases, their synthesis is based on the synthesis of known dendrimers, such as poly(aryl ether), poly(amidoamine) (in particular PAMAM), poly(amide) (in particular poly(L-lysine)), 1→3 branching motifs (instead of 1→2), poly(alkyl ether) (poly(glycerol) and poly(ethylene glycol)), poly(ester), and those containing main group elements (poly(carbosilane) and poly(phosphorhydrazone)). In most cases, the hydrophilic functions are on the surface of the dendrons, whereas one or two hydrophobic tails are linked to the core. Depending on the structure of the dendrons, and on the experimental conditions used, the amphiphilic dendrons can self-associate at the air-water interface, or form micelles (eventually tubular, but most generally spherical), or form vesicles. These associated dendrons are suitable for the encapsulation of low-molecular or macromolecular bioactive entities to be delivered in cells. This review is organized depending on the nature of the internal structure of the amphiphilic dendrons (aryl ether, amidoamine, amide, quaternary carbon atom, alkyl ether, ester, main group element). The properties issued from their self-associations are described all along the review.",
keywords = "amphiphiles, dendrons, encapsulation, micelles, self-association, Water, Dendrimers, Polyethylene Glycols, Micelles, Hydrophobic and Hydrophilic Interactions",
author = "Evgeny Apartsin and Caminade, {Anne Marie}",
note = "Funding Information: The project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sk{\l}odowska‐Curie grant agreement No 844217 for the MSCA‐IF‐2018 “EUREKA” to E.A. This article is based upon work from COST Action CA 17140 “Cancer Nanomedicine from the Bench to the Bedside” supported by COST (European Cooperation in Science and Technology). Thanks are also due to the CNRS for financial support. Publisher Copyright: {\textcopyright} 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH",
year = "2021",
month = dec,
day = "23",
doi = "10.1002/chem.202102589",
language = "English",
volume = "27",
pages = "17976--17998",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "72",

}

RIS

TY - JOUR

T1 - Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties

AU - Apartsin, Evgeny

AU - Caminade, Anne Marie

N1 - Funding Information: The project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska‐Curie grant agreement No 844217 for the MSCA‐IF‐2018 “EUREKA” to E.A. This article is based upon work from COST Action CA 17140 “Cancer Nanomedicine from the Bench to the Bedside” supported by COST (European Cooperation in Science and Technology). Thanks are also due to the CNRS for financial support. Publisher Copyright: © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH

PY - 2021/12/23

Y1 - 2021/12/23

N2 - This review presents precisely defined amphiphilic dendrons, their self-association properties, and their different uses. Dendrons, also named dendritic wedges, are composed of a core having two different types of functions, of which one type is used for growing or grafting branched arms, generally multiplied by 2 at each layer by using 1→2 branching motifs. A large diversity of structures has been already synthesized. In practically all cases, their synthesis is based on the synthesis of known dendrimers, such as poly(aryl ether), poly(amidoamine) (in particular PAMAM), poly(amide) (in particular poly(L-lysine)), 1→3 branching motifs (instead of 1→2), poly(alkyl ether) (poly(glycerol) and poly(ethylene glycol)), poly(ester), and those containing main group elements (poly(carbosilane) and poly(phosphorhydrazone)). In most cases, the hydrophilic functions are on the surface of the dendrons, whereas one or two hydrophobic tails are linked to the core. Depending on the structure of the dendrons, and on the experimental conditions used, the amphiphilic dendrons can self-associate at the air-water interface, or form micelles (eventually tubular, but most generally spherical), or form vesicles. These associated dendrons are suitable for the encapsulation of low-molecular or macromolecular bioactive entities to be delivered in cells. This review is organized depending on the nature of the internal structure of the amphiphilic dendrons (aryl ether, amidoamine, amide, quaternary carbon atom, alkyl ether, ester, main group element). The properties issued from their self-associations are described all along the review.

AB - This review presents precisely defined amphiphilic dendrons, their self-association properties, and their different uses. Dendrons, also named dendritic wedges, are composed of a core having two different types of functions, of which one type is used for growing or grafting branched arms, generally multiplied by 2 at each layer by using 1→2 branching motifs. A large diversity of structures has been already synthesized. In practically all cases, their synthesis is based on the synthesis of known dendrimers, such as poly(aryl ether), poly(amidoamine) (in particular PAMAM), poly(amide) (in particular poly(L-lysine)), 1→3 branching motifs (instead of 1→2), poly(alkyl ether) (poly(glycerol) and poly(ethylene glycol)), poly(ester), and those containing main group elements (poly(carbosilane) and poly(phosphorhydrazone)). In most cases, the hydrophilic functions are on the surface of the dendrons, whereas one or two hydrophobic tails are linked to the core. Depending on the structure of the dendrons, and on the experimental conditions used, the amphiphilic dendrons can self-associate at the air-water interface, or form micelles (eventually tubular, but most generally spherical), or form vesicles. These associated dendrons are suitable for the encapsulation of low-molecular or macromolecular bioactive entities to be delivered in cells. This review is organized depending on the nature of the internal structure of the amphiphilic dendrons (aryl ether, amidoamine, amide, quaternary carbon atom, alkyl ether, ester, main group element). The properties issued from their self-associations are described all along the review.

KW - amphiphiles

KW - dendrons

KW - encapsulation

KW - micelles

KW - self-association

KW - Water

KW - Dendrimers

KW - Polyethylene Glycols

KW - Micelles

KW - Hydrophobic and Hydrophilic Interactions

UR - http://www.scopus.com/inward/record.url?scp=85118200079&partnerID=8YFLogxK

U2 - 10.1002/chem.202102589

DO - 10.1002/chem.202102589

M3 - Review article

C2 - 34713506

AN - SCOPUS:85118200079

VL - 27

SP - 17976

EP - 17998

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 72

ER -

ID: 34599863