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Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis. / Serebrennikova, P. S.; Gromilov, S. A.

в: Journal of Structural Chemistry, Том 63, № 11, 11.2022, стр. 1856-1871.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Serebrennikova, PS & Gromilov, SA 2022, 'Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis', Journal of Structural Chemistry, Том. 63, № 11, стр. 1856-1871. https://doi.org/10.1134/S0022476622110166

APA

Serebrennikova, P. S., & Gromilov, S. A. (2022). Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis. Journal of Structural Chemistry, 63(11), 1856-1871. https://doi.org/10.1134/S0022476622110166

Vancouver

Serebrennikova PS, Gromilov SA. Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis. Journal of Structural Chemistry. 2022 нояб.;63(11):1856-1871. doi: 10.1134/S0022476622110166

Author

Serebrennikova, P. S. ; Gromilov, S. A. / Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis. в: Journal of Structural Chemistry. 2022 ; Том 63, № 11. стр. 1856-1871.

BibTeX

@article{0a7779e14531405794b66d2eeda4c4ab,
title = "Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis",
abstract = "By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH3)4]MoO4 and [Pd(NH3)4]CrO4 salts, [Pd(NH3)4](MoO4)x(CrO4)1–x solid solutions with x ranging from 0.05 to 0.80 are formed. To construct the V(x) dependence an original procedure of refining unit cell parameters is used. It is revealed that in the thermal decomposition of the [Pd(NH3)4](MoO4)0.18(CrO4)0.82 single crystal (composition is determined by the single crystal XRD analysis) a mixture of phases based on the fcc lattice of Pd (Pd0.88Cr0.10Mo0.01) and on Cr2O3 is formed.",
keywords = "accuracy, single crystal X-ray diffraction analysis, unit cell parameters, Vegard{\textquoteright}s law, X-ray diffraction of polycrystals, Zen{\textquoteright}s law",
author = "Serebrennikova, {P. S.} and Gromilov, {S. A.}",
note = "Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700313-8) and Priority 2030. Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",
year = "2022",
month = nov,
doi = "10.1134/S0022476622110166",
language = "English",
volume = "63",
pages = "1856--1871",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "11",

}

RIS

TY - JOUR

T1 - Study of [Pd(NH3)4](MoO4) x(CrO4)1–x solid solutions and products of their thermolysis

AU - Serebrennikova, P. S.

AU - Gromilov, S. A.

N1 - Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700313-8) and Priority 2030. Publisher Copyright: © 2022, Pleiades Publishing, Ltd.

PY - 2022/11

Y1 - 2022/11

N2 - By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH3)4]MoO4 and [Pd(NH3)4]CrO4 salts, [Pd(NH3)4](MoO4)x(CrO4)1–x solid solutions with x ranging from 0.05 to 0.80 are formed. To construct the V(x) dependence an original procedure of refining unit cell parameters is used. It is revealed that in the thermal decomposition of the [Pd(NH3)4](MoO4)0.18(CrO4)0.82 single crystal (composition is determined by the single crystal XRD analysis) a mixture of phases based on the fcc lattice of Pd (Pd0.88Cr0.10Mo0.01) and on Cr2O3 is formed.

AB - By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH3)4]MoO4 and [Pd(NH3)4]CrO4 salts, [Pd(NH3)4](MoO4)x(CrO4)1–x solid solutions with x ranging from 0.05 to 0.80 are formed. To construct the V(x) dependence an original procedure of refining unit cell parameters is used. It is revealed that in the thermal decomposition of the [Pd(NH3)4](MoO4)0.18(CrO4)0.82 single crystal (composition is determined by the single crystal XRD analysis) a mixture of phases based on the fcc lattice of Pd (Pd0.88Cr0.10Mo0.01) and on Cr2O3 is formed.

KW - accuracy

KW - single crystal X-ray diffraction analysis

KW - unit cell parameters

KW - Vegard’s law

KW - X-ray diffraction of polycrystals

KW - Zen’s law

UR - http://www.scopus.com/inward/record.url?scp=85143512298&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/26a7c321-2dd0-3cb9-bc51-75e38d7159f5/

U2 - 10.1134/S0022476622110166

DO - 10.1134/S0022476622110166

M3 - Article

AN - SCOPUS:85143512298

VL - 63

SP - 1856

EP - 1871

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 40503447