TY - JOUR

T1 - Structures and Properties of Polymeric Iodobismuthates Cat{[BiI4]} with Pyridinium-Derived Cations

AU - Shentseva, I. A.

AU - Usoltsev, A. N.

AU - Korobeynikov, N. A.

AU - Korolkov, I. V.

AU - Sokolov, M. N.

AU - Adonin, S. A.

N1 - This work was supported by the Russian Science Foundation (project no. 23-73-10054) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of samples, no. 121031700313-8).

PY - 2024/8/16

Y1 - 2024/8/16

N2 - Two novel bismuth(III) iodide complexes (1,3,4-MePy){[BiI4]} (1) and (3-Br-1-MePy){[BiI4]} (2)) were synthesized by the reaction of iodides of corresponding cations with BiI3 in organic solvents. Crystal structures of the compounds were determined by single crystal X-ray diffraction. For both complexes, the thermal stability was studied, and the optical band gap values were experimentally estimated.

AB - Two novel bismuth(III) iodide complexes (1,3,4-MePy){[BiI4]} (1) and (3-Br-1-MePy){[BiI4]} (2)) were synthesized by the reaction of iodides of corresponding cations with BiI3 in organic solvents. Crystal structures of the compounds were determined by single crystal X-ray diffraction. For both complexes, the thermal stability was studied, and the optical band gap values were experimentally estimated.

KW - bismuth

KW - coordination complex

KW - crystal structure

KW - halide complexes

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85201011305&origin=inward&txGid=6d581aed90da1ba7bc2628880a34c274

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001288090700025

UR - https://www.mendeley.com/catalogue/0a2463ae-1b9e-3264-84df-239f73299fb0/

U2 - 10.1134/S0036023624600254

DO - 10.1134/S0036023624600254

M3 - Article

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

ER -