Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structured catalysts for biofuels transformation into syngas with active components based on perovskite and spinel oxides supported on Mg-doped alumina. / Sadykov, Vladislav; Pavlova, Svetlana; Smal, Ekaterina и др.
в: Catalysis Today, Том 293, 15.09.2017, стр. 176-185.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structured catalysts for biofuels transformation into syngas with active components based on perovskite and spinel oxides supported on Mg-doped alumina
AU - Sadykov, Vladislav
AU - Pavlova, Svetlana
AU - Smal, Ekaterina
AU - Arapova, Marina
AU - Simonov, Mikhail
AU - Mezentseva, Natalia
AU - Rogov, Vladimir
AU - Glazneva, Tatiana
AU - Lukashevich, Anton
AU - Roger, Anne Cecile
AU - Parkhomenko, Ksenia
AU - van Veen, Andre
AU - Smorygo, Oleg
PY - 2017/9/15
Y1 - 2017/9/15
N2 - For structured catalysts of biofuels transformation into syngas inexpensive and stable to sintering active components based upon Mg-doped γ-alumina with supported LaNi0.9Ru0.1O3 perovskite or MnCr2O4 spinel promoted by Ru + Ni were developed. Characterization of the surface features, reactivity, catalytic activity and routes of ethanol transformation on these catalysts demonstrated that suppression of support acidity, strong interaction of Ru-Ni alloy nanoparticles with manganese chromite layers on support and a high redox ability provide a high yield of syngas and stability to coking. The most promising active component (2 wt% Ni + 2 wt% Ru)/MnCr2O4/10 wt% MgO − γ-Al2O3 supported on microchannel heat-conducting CrAlO cermet plates demonstrated a high performance and stability to coking in the autothermal reforming of such reactive fuels as glycerol, anisol and turpentine oil.
AB - For structured catalysts of biofuels transformation into syngas inexpensive and stable to sintering active components based upon Mg-doped γ-alumina with supported LaNi0.9Ru0.1O3 perovskite or MnCr2O4 spinel promoted by Ru + Ni were developed. Characterization of the surface features, reactivity, catalytic activity and routes of ethanol transformation on these catalysts demonstrated that suppression of support acidity, strong interaction of Ru-Ni alloy nanoparticles with manganese chromite layers on support and a high redox ability provide a high yield of syngas and stability to coking. The most promising active component (2 wt% Ni + 2 wt% Ru)/MnCr2O4/10 wt% MgO − γ-Al2O3 supported on microchannel heat-conducting CrAlO cermet plates demonstrated a high performance and stability to coking in the autothermal reforming of such reactive fuels as glycerol, anisol and turpentine oil.
KW - Biofuels
KW - Catalysis
KW - Coking stability
KW - Nanocomposites
KW - Syngas
KW - METHANE COMBUSTION
KW - LOW-TEMPERATURE
KW - OXYGEN
KW - NI/AL2O3 CATALYSTS
KW - HYDROGEN-PRODUCTION
KW - ETHANOL
KW - PARTIAL OXIDATION
KW - NI
KW - CO-ADSORPTION
KW - FUELS
UR - http://www.scopus.com/inward/record.url?scp=85020022597&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2017.05.055
DO - 10.1016/j.cattod.2017.05.055
M3 - Article
AN - SCOPUS:85020022597
VL - 293
SP - 176
EP - 185
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
ER -
ID: 10190023