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Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II). / Golovnev, N. N.; Molokeev, M. S.; Smolentsev, A. I. и др.

в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 43, № 2, 01.02.2017, стр. 82-85.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Golovnev, NN, Molokeev, MS, Smolentsev, AI & Lesnikov, MK 2017, 'Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том. 43, № 2, стр. 82-85. https://doi.org/10.1134/S1070328417010031

APA

Golovnev, N. N., Molokeev, M. S., Smolentsev, A. I., & Lesnikov, M. K. (2017). Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(2), 82-85. https://doi.org/10.1134/S1070328417010031

Vancouver

Golovnev NN, Molokeev MS, Smolentsev AI, Lesnikov MK. Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 февр. 1;43(2):82-85. doi: 10.1134/S1070328417010031

Author

Golovnev, N. N. ; Molokeev, M. S. ; Smolentsev, A. I. и др. / Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II). в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Том 43, № 2. стр. 82-85.

BibTeX

@article{30bb47a865a142f8bf2d3a3ae6e741db,
title = "Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)",
abstract = "The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) {\AA}, β = 92.196(2)°, V = 2996.1(3) {\AA}3, space group P21/c, Z = 2. The Co2+ ions in compound I are joined in pairs by bridging ligands μ2-Detba–−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО5. Hydrogen bonds O–H···O formed by BuOH and Detba– join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.",
keywords = "1,3-diethyl-2-thiobarbituric acid, butanol-1, cobalt(II), dimeric complex, IR spectrum, structure, ACID, CRYSTAL-STRUCTURE, THERMAL-PROPERTIES, COMPLEXES, 1,3-DIETHYL-2-THIOBARBITURATE",
author = "Golovnev, {N. N.} and Molokeev, {M. S.} and Smolentsev, {A. I.} and Lesnikov, {M. K.}",
year = "2017",
month = feb,
day = "1",
doi = "10.1134/S1070328417010031",
language = "English",
volume = "43",
pages = "82--85",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)

AU - Golovnev, N. N.

AU - Molokeev, M. S.

AU - Smolentsev, A. I.

AU - Lesnikov, M. K.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) Å, β = 92.196(2)°, V = 2996.1(3) Å3, space group P21/c, Z = 2. The Co2+ ions in compound I are joined in pairs by bridging ligands μ2-Detba–−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО5. Hydrogen bonds O–H···O formed by BuOH and Detba– join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.

AB - The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) Å, β = 92.196(2)°, V = 2996.1(3) Å3, space group P21/c, Z = 2. The Co2+ ions in compound I are joined in pairs by bridging ligands μ2-Detba–−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО5. Hydrogen bonds O–H···O formed by BuOH and Detba– join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.

KW - 1,3-diethyl-2-thiobarbituric acid

KW - butanol-1

KW - cobalt(II)

KW - dimeric complex

KW - IR spectrum

KW - structure

KW - ACID

KW - CRYSTAL-STRUCTURE

KW - THERMAL-PROPERTIES

KW - COMPLEXES

KW - 1,3-DIETHYL-2-THIOBARBITURATE

UR - http://www.scopus.com/inward/record.url?scp=85013469469&partnerID=8YFLogxK

U2 - 10.1134/S1070328417010031

DO - 10.1134/S1070328417010031

M3 - Article

AN - SCOPUS:85013469469

VL - 43

SP - 82

EP - 85

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

ID: 10308767