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Structure of lanthanum(III) tris-dipivaloylmethanate. / Yuikhan, Lu; Mosyagina, S. A.; Stabnikov, P. A. и др.

в: Journal of Structural Chemistry, Том 58, № 4, 01.07.2017, стр. 843-846.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Yuikhan, L, Mosyagina, SA, Stabnikov, PA, Alferova, NI, Korol‘kov, IV, Pervukhina, NV & Morozova, NB 2017, 'Structure of lanthanum(III) tris-dipivaloylmethanate', Journal of Structural Chemistry, Том. 58, № 4, стр. 843-846. https://doi.org/10.1134/S0022476617040333

APA

Yuikhan, L., Mosyagina, S. A., Stabnikov, P. A., Alferova, N. I., Korol‘kov, I. V., Pervukhina, N. V., & Morozova, N. B. (2017). Structure of lanthanum(III) tris-dipivaloylmethanate. Journal of Structural Chemistry, 58(4), 843-846. https://doi.org/10.1134/S0022476617040333

Vancouver

Yuikhan L, Mosyagina SA, Stabnikov PA, Alferova NI, Korol‘kov IV, Pervukhina NV и др. Structure of lanthanum(III) tris-dipivaloylmethanate. Journal of Structural Chemistry. 2017 июль 1;58(4):843-846. doi: 10.1134/S0022476617040333

Author

Yuikhan, Lu ; Mosyagina, S. A. ; Stabnikov, P. A. и др. / Structure of lanthanum(III) tris-dipivaloylmethanate. в: Journal of Structural Chemistry. 2017 ; Том 58, № 4. стр. 843-846.

BibTeX

@article{a6ef5268f5e143e7b37b8d2bc382326e,
title = "Structure of lanthanum(III) tris-dipivaloylmethanate",
abstract = "A series of Ln(III) dipivaloylmethanates of the composition Ln(dpm)3 (Ln = La, Tm, Yb) is obtained. It is established that Tm(dpm)3 and Yb(dpm)3 complexes are isostructural with Lu(dpm)3. The crystal structure of [La(dpm)3]2 at 150(2) K is determined (space group P21/n, a = 12.4412(5) {\AA}, b = 28.0579(12) {\AA}, с = 21.9533(8) {\AA}, β = 105.796(2)°, V = 7373.9(5) {\AA}3, Z = 4). The studied compound is isostructural with [Pr(dpm)3]2, [Eu(dpm)3]2, [Gd(dpm)3]2, and [Tb(dpm)3]2 complexes. The crystal structure of the complex is formed by dimeric [La(dpm)3]2 molecules. Thermogravimetric investigations show that the volatility of Ln(dpm)3 increases in the series from [La(dpm)3]2 to Yb(dpm)3. Melting points of the complexes are close to the known literature data.",
keywords = "crystal structure, Ln(III) dipivaloylmethanates, synthesis, volatility, CRYSTAL, BETA-DIKETONATE",
author = "Lu Yuikhan and Mosyagina, {S. A.} and Stabnikov, {P. A.} and Alferova, {N. I.} and Korol{\textquoteleft}kov, {I. V.} and Pervukhina, {N. V.} and Morozova, {N. B.}",
year = "2017",
month = jul,
day = "1",
doi = "10.1134/S0022476617040333",
language = "English",
volume = "58",
pages = "843--846",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Structure of lanthanum(III) tris-dipivaloylmethanate

AU - Yuikhan, Lu

AU - Mosyagina, S. A.

AU - Stabnikov, P. A.

AU - Alferova, N. I.

AU - Korol‘kov, I. V.

AU - Pervukhina, N. V.

AU - Morozova, N. B.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - A series of Ln(III) dipivaloylmethanates of the composition Ln(dpm)3 (Ln = La, Tm, Yb) is obtained. It is established that Tm(dpm)3 and Yb(dpm)3 complexes are isostructural with Lu(dpm)3. The crystal structure of [La(dpm)3]2 at 150(2) K is determined (space group P21/n, a = 12.4412(5) Å, b = 28.0579(12) Å, с = 21.9533(8) Å, β = 105.796(2)°, V = 7373.9(5) Å3, Z = 4). The studied compound is isostructural with [Pr(dpm)3]2, [Eu(dpm)3]2, [Gd(dpm)3]2, and [Tb(dpm)3]2 complexes. The crystal structure of the complex is formed by dimeric [La(dpm)3]2 molecules. Thermogravimetric investigations show that the volatility of Ln(dpm)3 increases in the series from [La(dpm)3]2 to Yb(dpm)3. Melting points of the complexes are close to the known literature data.

AB - A series of Ln(III) dipivaloylmethanates of the composition Ln(dpm)3 (Ln = La, Tm, Yb) is obtained. It is established that Tm(dpm)3 and Yb(dpm)3 complexes are isostructural with Lu(dpm)3. The crystal structure of [La(dpm)3]2 at 150(2) K is determined (space group P21/n, a = 12.4412(5) Å, b = 28.0579(12) Å, с = 21.9533(8) Å, β = 105.796(2)°, V = 7373.9(5) Å3, Z = 4). The studied compound is isostructural with [Pr(dpm)3]2, [Eu(dpm)3]2, [Gd(dpm)3]2, and [Tb(dpm)3]2 complexes. The crystal structure of the complex is formed by dimeric [La(dpm)3]2 molecules. Thermogravimetric investigations show that the volatility of Ln(dpm)3 increases in the series from [La(dpm)3]2 to Yb(dpm)3. Melting points of the complexes are close to the known literature data.

KW - crystal structure

KW - Ln(III) dipivaloylmethanates

KW - synthesis

KW - volatility

KW - CRYSTAL

KW - BETA-DIKETONATE

UR - http://www.scopus.com/inward/record.url?scp=85029600341&partnerID=8YFLogxK

U2 - 10.1134/S0022476617040333

DO - 10.1134/S0022476617040333

M3 - Article

AN - SCOPUS:85029600341

VL - 58

SP - 843

EP - 846

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 9079996