Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4. / Kuratieva, N. V.; Vikulova, E. S.; Shushanyan, A. D. и др.
в: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 1004-1008.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4
AU - Kuratieva, N. V.
AU - Vikulova, E. S.
AU - Shushanyan, A. D.
AU - Nikolaeva, N. S.
AU - Dorovskikh, S. I.
AU - Mikhaleva, N. S.
AU - Morozova, N. B.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.
AB - Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.
KW - copper(II)
KW - palladium(II)
KW - single crystal X-ray diffraction
KW - β-iminoketone
KW - PALLADIUM
KW - CHEMICAL-VAPOR-DEPOSITION
KW - MEMBRANES
KW - PRECURSORS
KW - beta-iminoketone
UR - http://www.scopus.com/inward/record.url?scp=85032307837&partnerID=8YFLogxK
U2 - 10.1134/S0022476617050213
DO - 10.1134/S0022476617050213
M3 - Article
AN - SCOPUS:85032307837
VL - 58
SP - 1004
EP - 1008
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 5
ER -
ID: 9873719