Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model. / Stovbun, S. V.; Zanin, A. M.; Mikhaleva, M. G. и др.
в: High Energy Chemistry, Том 52, № 5, 01.09.2018, стр. 369-372.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model
AU - Stovbun, S. V.
AU - Zanin, A. M.
AU - Mikhaleva, M. G.
AU - Skoblin, A. A.
AU - Tverdislov, V. A.
AU - Taran, O. P.
AU - Parmon, V. N.
PY - 2018/9/1
Y1 - 2018/9/1
N2 - The structure formation in xerogels of aqueous solutions of products of the UV-initiated formose reaction has been studied in the context of the problem of the spontaneous formation of prebiological structures. Of the 11 variants of xerogels, only in the talopyranose xerogel show the presence of anisometric strings with distinct periodic (in particular, helical) structure, which form characteristic elements of biomimetic structures by interlacing. Under the conditions simulating the primitive Earth’s atmosphere (formaldehyde, water, UV), spontaneous formation of anisometric superhelical structures has been modeled and the type of the sugars forming these structures has been identified.
AB - The structure formation in xerogels of aqueous solutions of products of the UV-initiated formose reaction has been studied in the context of the problem of the spontaneous formation of prebiological structures. Of the 11 variants of xerogels, only in the talopyranose xerogel show the presence of anisometric strings with distinct periodic (in particular, helical) structure, which form characteristic elements of biomimetic structures by interlacing. Under the conditions simulating the primitive Earth’s atmosphere (formaldehyde, water, UV), spontaneous formation of anisometric superhelical structures has been modeled and the type of the sugars forming these structures has been identified.
KW - anisometry
KW - formose reaction
KW - photoionization
KW - prebiological evolution
KW - supercoiling
UR - http://www.scopus.com/inward/record.url?scp=85053398185&partnerID=8YFLogxK
U2 - 10.1134/S0018143918050156
DO - 10.1134/S0018143918050156
M3 - Article
AN - SCOPUS:85053398185
VL - 52
SP - 369
EP - 372
JO - High Energy Chemistry
JF - High Energy Chemistry
SN - 0018-1439
IS - 5
ER -
ID: 16601340