Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Solid solutions in EuSc3(BO3)4-GdSc3(BO3)4 system: Phase diagram, synthesis, crystal growth, structure and luminescence. / Kokh, Alexander; Kuznetsov, Artem; Khan, Elona и др.
в: Journal of Crystal Growth, Том 645, 127842, 01.11.2024.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Solid solutions in EuSc3(BO3)4-GdSc3(BO3)4 system: Phase diagram, synthesis, crystal growth, structure and luminescence
AU - Kokh, Alexander
AU - Kuznetsov, Artem
AU - Khan, Elona
AU - Simonova, Ekaterina
AU - Ryadun, Alexey
AU - Lapin, Ivan
AU - Svetlichnyi, Valery
AU - Kokh, Konstantin
N1 - The work was supported by Russian Science Foundation N◦ 23-19-00617.
PY - 2024/11/1
Y1 - 2024/11/1
N2 - Solid solutions based on (Eu,Gd)Sc3(BO3)4 (C2/c) and Gd0.25Sc0.75BO3 (R 3¯) in the EuSc3(BO3)4-GdSc3(BO3)4 system were studied. Synthesis at 1250 °C provides wide homogeneity regions which are stable at room temperature. Melt-solution crystallization of both compounds from LiBO2-LiF flux was shown. All the obtained samples have luminescence characteristic of Eu3+ with a largest peak at 615 nm corresponding to the 5D0 → 7F2 transition. In this series the luminescence intensity monotonically increases with an increase of Eu content. The largest quantum yield of luminescence (53 %) in the EuSc3(BO3)4-GdSc3(BO3)4 system is demonstrated by EuSc3(BO3)4 sample.
AB - Solid solutions based on (Eu,Gd)Sc3(BO3)4 (C2/c) and Gd0.25Sc0.75BO3 (R 3¯) in the EuSc3(BO3)4-GdSc3(BO3)4 system were studied. Synthesis at 1250 °C provides wide homogeneity regions which are stable at room temperature. Melt-solution crystallization of both compounds from LiBO2-LiF flux was shown. All the obtained samples have luminescence characteristic of Eu3+ with a largest peak at 615 nm corresponding to the 5D0 → 7F2 transition. In this series the luminescence intensity monotonically increases with an increase of Eu content. The largest quantum yield of luminescence (53 %) in the EuSc3(BO3)4-GdSc3(BO3)4 system is demonstrated by EuSc3(BO3)4 sample.
KW - Eu3+
KW - Lifetime
KW - Luminescence
KW - Quantum yield
KW - Rare earth borate
KW - Structure
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85201103037&origin=inward&txGid=4112dbd2588515518fb89841d07854f3
UR - https://www.mendeley.com/catalogue/1a65d435-7866-34cd-b151-2561477037c1/
U2 - 10.1016/j.jcrysgro.2024.127842
DO - 10.1016/j.jcrysgro.2024.127842
M3 - Article
VL - 645
JO - Journal of Crystal Growth
JF - Journal of Crystal Growth
SN - 0022-0248
M1 - 127842
ER -
ID: 60385392