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Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon. / Veselov, Grigory B.; Karnaukhov, Timofey M.; Bauman, Yury I. и др.

в: Materials, Том 13, № 19, 4404, 01.10.2020, стр. 1-12.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Veselov, GB, Karnaukhov, TM, Bauman, YI, Mishakov, IV & Vedyagin, AA 2020, 'Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon', Materials, Том. 13, № 19, 4404, стр. 1-12. https://doi.org/10.3390/ma13194404

APA

Vancouver

Veselov GB, Karnaukhov TM, Bauman YI, Mishakov IV, Vedyagin AA. Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon. Materials. 2020 окт. 1;13(19):1-12. 4404. doi: 10.3390/ma13194404

Author

Veselov, Grigory B. ; Karnaukhov, Timofey M. ; Bauman, Yury I. и др. / Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon. в: Materials. 2020 ; Том 13, № 19. стр. 1-12.

BibTeX

@article{a6785c6e80224d8590f80f26061e79ab,
title = "Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon",
abstract = "The present work aimed to prepare Ni-Mo particles distributed within the MgO matrix. With this purpose in mind, a ternary Ni-Mo-Mg oxide system was synthesized by a sol-gel approach. The samples were studied by low-temperature nitrogen adsorption, X-ray diffraction analysis, and transmission electron microscopy equipped with energy dispersive X-ray analysis. Both the nickel and molybdenum species in the prepared samples were characterized by a fine and uniform distribution. The diffraction pattern of the ternary system was predominantly represented by the MgO reflections. The catalytic activity of the samples was tested in the decomposition of 1,2-dichloroethane used as a representative of the chlorinated organic wastes. The nanostructured carbon filaments resulting from the decomposition of the halogenated substrate were found to be characterized by a narrow diameter distribution, according to the transmission electron microscopy data, thus confirming the fine distribution of the active Ni-Mo particles. The results obviously show the advantages of the sol-gel technique for obtaining efficient catalysts.",
keywords = "Catalytic activity, CCVD, Filamentous carbon formation, Particles{\textquoteright} distribution, Ternary oxide system",
author = "Veselov, {Grigory B.} and Karnaukhov, {Timofey M.} and Bauman, {Yury I.} and Mishakov, {Ilya V.} and Vedyagin, {Aleksey A.}",
note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = oct,
day = "1",
doi = "10.3390/ma13194404",
language = "English",
volume = "13",
pages = "1--12",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "19",

}

RIS

TY - JOUR

T1 - Sol-gel-prepared ni-mo-mg-o system for catalytic transformation of chlorinated organic wastes into nanostructured carbon

AU - Veselov, Grigory B.

AU - Karnaukhov, Timofey M.

AU - Bauman, Yury I.

AU - Mishakov, Ilya V.

AU - Vedyagin, Aleksey A.

N1 - Publisher Copyright: © 2020 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/10/1

Y1 - 2020/10/1

N2 - The present work aimed to prepare Ni-Mo particles distributed within the MgO matrix. With this purpose in mind, a ternary Ni-Mo-Mg oxide system was synthesized by a sol-gel approach. The samples were studied by low-temperature nitrogen adsorption, X-ray diffraction analysis, and transmission electron microscopy equipped with energy dispersive X-ray analysis. Both the nickel and molybdenum species in the prepared samples were characterized by a fine and uniform distribution. The diffraction pattern of the ternary system was predominantly represented by the MgO reflections. The catalytic activity of the samples was tested in the decomposition of 1,2-dichloroethane used as a representative of the chlorinated organic wastes. The nanostructured carbon filaments resulting from the decomposition of the halogenated substrate were found to be characterized by a narrow diameter distribution, according to the transmission electron microscopy data, thus confirming the fine distribution of the active Ni-Mo particles. The results obviously show the advantages of the sol-gel technique for obtaining efficient catalysts.

AB - The present work aimed to prepare Ni-Mo particles distributed within the MgO matrix. With this purpose in mind, a ternary Ni-Mo-Mg oxide system was synthesized by a sol-gel approach. The samples were studied by low-temperature nitrogen adsorption, X-ray diffraction analysis, and transmission electron microscopy equipped with energy dispersive X-ray analysis. Both the nickel and molybdenum species in the prepared samples were characterized by a fine and uniform distribution. The diffraction pattern of the ternary system was predominantly represented by the MgO reflections. The catalytic activity of the samples was tested in the decomposition of 1,2-dichloroethane used as a representative of the chlorinated organic wastes. The nanostructured carbon filaments resulting from the decomposition of the halogenated substrate were found to be characterized by a narrow diameter distribution, according to the transmission electron microscopy data, thus confirming the fine distribution of the active Ni-Mo particles. The results obviously show the advantages of the sol-gel technique for obtaining efficient catalysts.

KW - Catalytic activity

KW - CCVD

KW - Filamentous carbon formation

KW - Particles’ distribution

KW - Ternary oxide system

UR - http://www.scopus.com/inward/record.url?scp=85093957713&partnerID=8YFLogxK

U2 - 10.3390/ma13194404

DO - 10.3390/ma13194404

M3 - Article

C2 - 33023242

AN - SCOPUS:85093957713

VL - 13

SP - 1

EP - 12

JO - Materials

JF - Materials

SN - 1996-1944

IS - 19

M1 - 4404

ER -

ID: 25865366