Standard

Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior. / Vorotnikova, Natalya A.; Berezin, Alexey S.; Eltsov, Ilia V. и др.

в: Inorganica Chimica Acta, Том 582, 122656, 01.07.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Vorotnikova, NA, Berezin, AS, Eltsov, IV, Sukhikh, TS, Shestopalov, MA & Vorotnikov, YA 2025, 'Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior', Inorganica Chimica Acta, Том. 582, 122656. https://doi.org/10.1016/j.ica.2025.122656

APA

Vorotnikova, N. A., Berezin, A. S., Eltsov, I. V., Sukhikh, T. S., Shestopalov, M. A., & Vorotnikov, Y. A. (2025). Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior. Inorganica Chimica Acta, 582, [122656]. https://doi.org/10.1016/j.ica.2025.122656

Vancouver

Vorotnikova NA, Berezin AS, Eltsov IV, Sukhikh TS, Shestopalov MA, Vorotnikov YA. Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior. Inorganica Chimica Acta. 2025 июль 1;582:122656. doi: 10.1016/j.ica.2025.122656

Author

Vorotnikova, Natalya A. ; Berezin, Alexey S. ; Eltsov, Ilia V. и др. / Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior. в: Inorganica Chimica Acta. 2025 ; Том 582.

BibTeX

@article{762d5d0c17c74ef3881b7e68dc32dd5f,
title = "Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior",
abstract = "Despite the high practical potential of octahedral iodide molybdenum cluster complexes [M6I8L6]n, their further development is still hindered due to their hydrolytic instability. Some success in stabilizing the complexes in aqueous solutions has been achieved by using certain ligands, but so far, the type of ligand still has an unpredictable influence on the stability of these compounds. Therefore, obtaining new water-soluble clusters and studying their behavior in aqueous medium is an urgent task. In this work, a new representative of cluster compounds – Na2[Mo6I8(GA)6] (where GA− is an anion of glycolic acid) – has been synthesized and characterized in detail. The study of its hydrolytic stability showed the formation of an insoluble mixed-ligand neutral complex – trans-[Mo6I8(H2O)2(GA)4], which is a first example of the cluster of such type bearing carboxylate ligands. Photoluminescence was studied for the obtained compounds.",
keywords = "Hydrolysis, Luminescence, Octahedral iodide molybdenum cluster",
author = "Vorotnikova, {Natalya A.} and Berezin, {Alexey S.} and Eltsov, {Ilia V.} and Sukhikh, {Taisiya S.} and Shestopalov, {Michael A.} and Vorotnikov, {Yuri A.}",
note = "This work was supported by the Russian Science Foundation (Grant № 23-73-01165)",
year = "2025",
month = jul,
day = "1",
doi = "10.1016/j.ica.2025.122656",
language = "English",
volume = "582",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier Science Publishing Company, Inc.",

}

RIS

TY - JOUR

T1 - Sodium salt of octahedral molybdenum iodide cluster with glycolate ligands and its hydrolytic behavior

AU - Vorotnikova, Natalya A.

AU - Berezin, Alexey S.

AU - Eltsov, Ilia V.

AU - Sukhikh, Taisiya S.

AU - Shestopalov, Michael A.

AU - Vorotnikov, Yuri A.

N1 - This work was supported by the Russian Science Foundation (Grant № 23-73-01165)

PY - 2025/7/1

Y1 - 2025/7/1

N2 - Despite the high practical potential of octahedral iodide molybdenum cluster complexes [M6I8L6]n, their further development is still hindered due to their hydrolytic instability. Some success in stabilizing the complexes in aqueous solutions has been achieved by using certain ligands, but so far, the type of ligand still has an unpredictable influence on the stability of these compounds. Therefore, obtaining new water-soluble clusters and studying their behavior in aqueous medium is an urgent task. In this work, a new representative of cluster compounds – Na2[Mo6I8(GA)6] (where GA− is an anion of glycolic acid) – has been synthesized and characterized in detail. The study of its hydrolytic stability showed the formation of an insoluble mixed-ligand neutral complex – trans-[Mo6I8(H2O)2(GA)4], which is a first example of the cluster of such type bearing carboxylate ligands. Photoluminescence was studied for the obtained compounds.

AB - Despite the high practical potential of octahedral iodide molybdenum cluster complexes [M6I8L6]n, their further development is still hindered due to their hydrolytic instability. Some success in stabilizing the complexes in aqueous solutions has been achieved by using certain ligands, but so far, the type of ligand still has an unpredictable influence on the stability of these compounds. Therefore, obtaining new water-soluble clusters and studying their behavior in aqueous medium is an urgent task. In this work, a new representative of cluster compounds – Na2[Mo6I8(GA)6] (where GA− is an anion of glycolic acid) – has been synthesized and characterized in detail. The study of its hydrolytic stability showed the formation of an insoluble mixed-ligand neutral complex – trans-[Mo6I8(H2O)2(GA)4], which is a first example of the cluster of such type bearing carboxylate ligands. Photoluminescence was studied for the obtained compounds.

KW - Hydrolysis

KW - Luminescence

KW - Octahedral iodide molybdenum cluster

UR - https://www.mendeley.com/catalogue/94a0fd23-7953-3096-aef3-85ba98867999/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105000365263&origin=inward&txGid=a601c473c7613374e1eb35b2795bee22

U2 - 10.1016/j.ica.2025.122656

DO - 10.1016/j.ica.2025.122656

M3 - Article

VL - 582

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 122656

ER -

ID: 65123256