Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Silicon doping effect on the properties of the hydrotreating catalysts of FCC feedstock pretreatment. / Nadeina, K. A.; Danilevich, V. V.; Kazakov, M. O. и др.
в: Applied Catalysis B: Environmental, Том 280, 119415, 01.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Silicon doping effect on the properties of the hydrotreating catalysts of FCC feedstock pretreatment
AU - Nadeina, K. A.
AU - Danilevich, V. V.
AU - Kazakov, M. O.
AU - Romanova, T. S.
AU - Gabrienko, A. A.
AU - Danilova, I. G.
AU - Pakharukova, V. A.
AU - Nikolaeva, O. A.
AU - Gerasimov, E. Yu
AU - Prosvirin, I. P.
AU - Kondrashev, D. O.
AU - Kleimenov, A. V.
AU - Klimov, O. V.
AU - Noskov, A. S.
PY - 2021/1
Y1 - 2021/1
N2 - Influence of Si addition at the stage of boehmite preparation on properties of NiMo/Al2O3 catalysts for FCC feedstock pretreatment have been studied. The series of boehmites doped by PDMS at the stage of hydrothermal treatment was prepared. Si/Al molar ratio was 0, 0.01, 0.015 and 0.02. Boehmites were used for supports and catalysts preparation. Boehmites, supports and catalysts have been characterized by XRD, TGA, nitrogen adsorption-desorption, IR spectroscopy, UV–Vis, 29Si MAS NMR, HRTEM, EDX, XPS. Catalysts were tested in hydrotreating of FCC feedstock. It is shown that there are changes in morphology of boehmite particles and textural characteristics of aluminas. Introduction of Si to alumina induces formation of wider mesopores and blocks part of the Lewis acid sites of alumina. Testing of catalysts in hydrotreating of FCC feedstock shows that the catalyst with Si/Al ratio of 0.01 in boehmite has the best combination of hydrodesulfurization and hydrodenitrogenation activities.
AB - Influence of Si addition at the stage of boehmite preparation on properties of NiMo/Al2O3 catalysts for FCC feedstock pretreatment have been studied. The series of boehmites doped by PDMS at the stage of hydrothermal treatment was prepared. Si/Al molar ratio was 0, 0.01, 0.015 and 0.02. Boehmites were used for supports and catalysts preparation. Boehmites, supports and catalysts have been characterized by XRD, TGA, nitrogen adsorption-desorption, IR spectroscopy, UV–Vis, 29Si MAS NMR, HRTEM, EDX, XPS. Catalysts were tested in hydrotreating of FCC feedstock. It is shown that there are changes in morphology of boehmite particles and textural characteristics of aluminas. Introduction of Si to alumina induces formation of wider mesopores and blocks part of the Lewis acid sites of alumina. Testing of catalysts in hydrotreating of FCC feedstock shows that the catalyst with Si/Al ratio of 0.01 in boehmite has the best combination of hydrodesulfurization and hydrodenitrogenation activities.
KW - boehmite
KW - hydrodenitrogenation
KW - Hydrodesulfurization
KW - silicon
KW - vacuum gas oil
KW - CRACKING
KW - NITROGEN-COMPOUNDS
KW - PERFORMANCE
KW - HYDRODESULFURIZATION
KW - DIBENZOTHIOPHENE
KW - ALUMINA
KW - NIMO CATALYSTS
KW - HDS CATALYSTS
KW - SPECTROSCOPIC CHARACTERIZATION
KW - SURFACE
UR - http://www.scopus.com/inward/record.url?scp=85089656465&partnerID=8YFLogxK
U2 - 10.1016/j.apcatb.2020.119415
DO - 10.1016/j.apcatb.2020.119415
M3 - Article
AN - SCOPUS:85089656465
VL - 280
JO - Applied Catalysis B: Environmental
JF - Applied Catalysis B: Environmental
SN - 0926-3373
M1 - 119415
ER -
ID: 25287544