Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Selective Single-Site Pd-In Hydrogenation Catalyst for Production of Enhanced Magnetic Resonance Signals using Parahydrogen. / Burueva, Dudari B.; Kovtunov, Kirill V.; Bukhtiyarov, Andrey V. и др.
в: Chemistry - A European Journal, Том 24, № 11, 21.02.2018, стр. 2547-2553.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Selective Single-Site Pd-In Hydrogenation Catalyst for Production of Enhanced Magnetic Resonance Signals using Parahydrogen
AU - Burueva, Dudari B.
AU - Kovtunov, Kirill V.
AU - Bukhtiyarov, Andrey V.
AU - Barskiy, Danila A.
AU - Prosvirin, Igor P.
AU - Mashkovsky, Igor S.
AU - Baeva, Galina N.
AU - Bukhtiyarov, Valerii I.
AU - Stakheev, Aleksandr Yu
AU - Koptyug, Igor V.
N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2018/2/21
Y1 - 2018/2/21
N2 - Pd-In/Al2O3 single-site catalyst was able to show high selectivity (up to 98%) in the gas phase semihydrogenation of propyne. Formation of intermetallic Pd-In compound was studied by XPS during reduction of the catalyst. FTIR-CO spectroscopy confirmed single-site nature of the intermetallic Pd-In phase reduced at high temperature. Utilization of Pd-In/Al2O3 in semihydrogenation of propyne with parahydrogen allowed to produce ≈3400-fold NMR signal enhancement for reaction product propene (polarization=9.3%), demonstrating the large contribution of pairwise hydrogen addition route. Significant signal enhancement as well as the high catalytic activity of the Pd-In catalyst allowed to acquire 1HMR images of flowing hyperpolarized propene gas selectively for protons in CH, CH2 and CH3 groups. This observation is unique and can be easily transferred to the development of a useful MRI technique for an in situ investigation of selective semihydrogenation in catalytic reactors.
AB - Pd-In/Al2O3 single-site catalyst was able to show high selectivity (up to 98%) in the gas phase semihydrogenation of propyne. Formation of intermetallic Pd-In compound was studied by XPS during reduction of the catalyst. FTIR-CO spectroscopy confirmed single-site nature of the intermetallic Pd-In phase reduced at high temperature. Utilization of Pd-In/Al2O3 in semihydrogenation of propyne with parahydrogen allowed to produce ≈3400-fold NMR signal enhancement for reaction product propene (polarization=9.3%), demonstrating the large contribution of pairwise hydrogen addition route. Significant signal enhancement as well as the high catalytic activity of the Pd-In catalyst allowed to acquire 1HMR images of flowing hyperpolarized propene gas selectively for protons in CH, CH2 and CH3 groups. This observation is unique and can be easily transferred to the development of a useful MRI technique for an in situ investigation of selective semihydrogenation in catalytic reactors.
KW - Bimetallic catalysts
KW - Heterogeneous hydrogenation
KW - MRI
KW - Parahydrogen
KW - Parahydrogen-induced polarization
KW - bimetallic catalysts
KW - parahydrogen-induced polarization
KW - parahydrogen
KW - heterogeneous hydrogenation
KW - HETEROGENEOUS HYDROGENATION
KW - LIQUID-PHASE HYDROGENATION
KW - TRIPLE BONDS
KW - SENSITIVITY
KW - PAIRWISE
KW - NANOPARTICLES
KW - SPECTROSCOPY
KW - INDUCED POLARIZATION
KW - HYPERPOLARIZATION
KW - SEMIHYDROGENATION
UR - http://www.scopus.com/inward/record.url?scp=85041099380&partnerID=8YFLogxK
U2 - 10.1002/chem.201705644
DO - 10.1002/chem.201705644
M3 - Article
C2 - 29322571
AN - SCOPUS:85041099380
VL - 24
SP - 2547
EP - 2553
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 11
ER -
ID: 9445035