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Samarium Polystibides Derived from Highly Activated Nanoscale Antimony. / Schoo, Christoph; Bestgen, Sebastian; Egeberg, Alexander и др.

в: Angewandte Chemie - International Edition, Том 57, № 20, 14.05.2018, стр. 5912-5916.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Schoo, C, Bestgen, S, Egeberg, A, Klementyeva, S, Feldmann, C, Konchenko, SN & Roesky, PW 2018, 'Samarium Polystibides Derived from Highly Activated Nanoscale Antimony', Angewandte Chemie - International Edition, Том. 57, № 20, стр. 5912-5916. https://doi.org/10.1002/anie.201802250

APA

Schoo, C., Bestgen, S., Egeberg, A., Klementyeva, S., Feldmann, C., Konchenko, S. N., & Roesky, P. W. (2018). Samarium Polystibides Derived from Highly Activated Nanoscale Antimony. Angewandte Chemie - International Edition, 57(20), 5912-5916. https://doi.org/10.1002/anie.201802250

Vancouver

Schoo C, Bestgen S, Egeberg A, Klementyeva S, Feldmann C, Konchenko SN и др. Samarium Polystibides Derived from Highly Activated Nanoscale Antimony. Angewandte Chemie - International Edition. 2018 май 14;57(20):5912-5916. doi: 10.1002/anie.201802250

Author

Schoo, Christoph ; Bestgen, Sebastian ; Egeberg, Alexander и др. / Samarium Polystibides Derived from Highly Activated Nanoscale Antimony. в: Angewandte Chemie - International Edition. 2018 ; Том 57, № 20. стр. 5912-5916.

BibTeX

@article{c8aeb7ddaaf647b9a4cd5674e053b00c,
title = "Samarium Polystibides Derived from Highly Activated Nanoscale Antimony",
abstract = "Zintl ions in molecular compounds are of fundamental interest for basic research and application. Two reactive antimony sources are presented that allow direct access to molecular polystibide compounds. These are Sb amalgam (Sb/Hg) and ultrasmall Sb0 nanoparticles (d=6.6±0.8nm), which were used independently as precursors for the synthesis of the largest f-element polystibide, [(Cp*2Sm)4Sb8]. Whereas the reaction of the nanoparticles with [Cp*2Sm] directly led to [(Cp*2Sm)4Sb8], Sm/Sb/Hg intermediates were isolated when using Sb/Hg as the precursor. These Sm/Sb/Hg intermediates [((Cp*2Sm)2Sb)2(μ-Hg)] and [((Cp*2Sm)3(μ4,η1:2:2:2-Sb4))2Hg] were synthetically trapped and structurally characterized, giving insight in the formation mechanism of polystibide compounds.",
keywords = "Activation, Antimony, Nanoparticles, Polystibides, Samarium, samarium, COMPLEX, antimony, ZINTL IONS, BOND FORMATION, REDUCTANTS, RAY CRYSTAL-STRUCTURE, NANOPARTICLES, nanoparticles, REDUCTION, CLUSTERS, RARE-EARTH-ELEMENTS, (C5ME5)2SM, activation, polystibides",
author = "Christoph Schoo and Sebastian Bestgen and Alexander Egeberg and Svetlana Klementyeva and Claus Feldmann and Konchenko, {Sergey N.} and Roesky, {Peter W.}",
note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2018",
month = may,
day = "14",
doi = "10.1002/anie.201802250",
language = "English",
volume = "57",
pages = "5912--5916",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "20",

}

RIS

TY - JOUR

T1 - Samarium Polystibides Derived from Highly Activated Nanoscale Antimony

AU - Schoo, Christoph

AU - Bestgen, Sebastian

AU - Egeberg, Alexander

AU - Klementyeva, Svetlana

AU - Feldmann, Claus

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2018/5/14

Y1 - 2018/5/14

N2 - Zintl ions in molecular compounds are of fundamental interest for basic research and application. Two reactive antimony sources are presented that allow direct access to molecular polystibide compounds. These are Sb amalgam (Sb/Hg) and ultrasmall Sb0 nanoparticles (d=6.6±0.8nm), which were used independently as precursors for the synthesis of the largest f-element polystibide, [(Cp*2Sm)4Sb8]. Whereas the reaction of the nanoparticles with [Cp*2Sm] directly led to [(Cp*2Sm)4Sb8], Sm/Sb/Hg intermediates were isolated when using Sb/Hg as the precursor. These Sm/Sb/Hg intermediates [((Cp*2Sm)2Sb)2(μ-Hg)] and [((Cp*2Sm)3(μ4,η1:2:2:2-Sb4))2Hg] were synthetically trapped and structurally characterized, giving insight in the formation mechanism of polystibide compounds.

AB - Zintl ions in molecular compounds are of fundamental interest for basic research and application. Two reactive antimony sources are presented that allow direct access to molecular polystibide compounds. These are Sb amalgam (Sb/Hg) and ultrasmall Sb0 nanoparticles (d=6.6±0.8nm), which were used independently as precursors for the synthesis of the largest f-element polystibide, [(Cp*2Sm)4Sb8]. Whereas the reaction of the nanoparticles with [Cp*2Sm] directly led to [(Cp*2Sm)4Sb8], Sm/Sb/Hg intermediates were isolated when using Sb/Hg as the precursor. These Sm/Sb/Hg intermediates [((Cp*2Sm)2Sb)2(μ-Hg)] and [((Cp*2Sm)3(μ4,η1:2:2:2-Sb4))2Hg] were synthetically trapped and structurally characterized, giving insight in the formation mechanism of polystibide compounds.

KW - Activation

KW - Antimony

KW - Nanoparticles

KW - Polystibides

KW - Samarium

KW - samarium

KW - COMPLEX

KW - antimony

KW - ZINTL IONS

KW - BOND FORMATION

KW - REDUCTANTS

KW - RAY CRYSTAL-STRUCTURE

KW - NANOPARTICLES

KW - nanoparticles

KW - REDUCTION

KW - CLUSTERS

KW - RARE-EARTH-ELEMENTS

KW - (C5ME5)2SM

KW - activation

KW - polystibides

UR - http://www.scopus.com/inward/record.url?scp=85045305469&partnerID=8YFLogxK

U2 - 10.1002/anie.201802250

DO - 10.1002/anie.201802250

M3 - Article

C2 - 29528543

AN - SCOPUS:85045305469

VL - 57

SP - 5912

EP - 5916

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 20

ER -

ID: 12543217