TY - JOUR

T1 - Role of Mixing and Milling in Mechanochemical Synthesis (Review)

AU - Lapshin, O. V.

AU - Boldyreva, E. V.

AU - Boldyrev, V. V.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research through project No. 19-13-50127 “Ekspansiya.” Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3

Y1 - 2021/3

N2 - Selected topics of inorganic mechanochemical synthesis are discussed. Variant mechanochemical syntheses are considered. The ex situ and in situ/operando methods to monitor the process are discussed. Methods for controlling the yield and kinetics of the mechanochemical synthesis are considered. The challenges and possible ways to address them are discussed. Thermal and mechanochemical syntheses are compared, with a special focus on mixing and milling processes. We consider the effects of various types of mechanical treatment on individual particles and on their mixtures. A special attention is paid to the macrokinetics of mechanochemical synthesis and its role in mixing and milling. The basic assumptions that render a mathematical model capable of describing the macrokinetics of mechanochemical synthesis in solid + reactive gas and solid + solid systems are written.

AB - Selected topics of inorganic mechanochemical synthesis are discussed. Variant mechanochemical syntheses are considered. The ex situ and in situ/operando methods to monitor the process are discussed. Methods for controlling the yield and kinetics of the mechanochemical synthesis are considered. The challenges and possible ways to address them are discussed. Thermal and mechanochemical syntheses are compared, with a special focus on mixing and milling processes. We consider the effects of various types of mechanical treatment on individual particles and on their mixtures. A special attention is paid to the macrokinetics of mechanochemical synthesis and its role in mixing and milling. The basic assumptions that render a mathematical model capable of describing the macrokinetics of mechanochemical synthesis in solid + reactive gas and solid + solid systems are written.

KW - ceramic materials

KW - in situ/operando studies

KW - macrokinetics

KW - mathematical modeling

KW - mechanical alloying

KW - mechanochemistry

KW - milling

KW - mixing

KW - nonthermal transformations

KW - SHS

UR - http://www.scopus.com/inward/record.url?scp=85102776595&partnerID=8YFLogxK

UR - https://www.elibrary.ru/item.asp?id=46759791

UR - https://www.mendeley.com/catalogue/e2b7e7a1-24ef-3f63-adb8-aec73f6f0c0a/

U2 - 10.1134/S0036023621030116

DO - 10.1134/S0036023621030116

M3 - Article

AN - SCOPUS:85102776595

VL - 66

SP - 433

EP - 453

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 3

M1 - 19

ER -