Rigid 1D Coordination Polymers with Tunable Metal Cation and Chiral Pendant Moieties

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Rigid 1D Coordination Polymers with Tunable Metal Cation and Chiral Pendant Moieties. / Zavakhina, Marina S.; Samsonenko, Denis G.; Dybtsev, Danil N. и др.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 641, № 3-4, 03.2015, стр. 590-595.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{04ac3402e2a3411092a800e6efce7745,

title = "Rigid 1D Coordination Polymers with Tunable Metal Cation and Chiral Pendant Moieties",

abstract = "A series of homochiral chain coordination polymers, based on structurally robust 4,4′-bipyridyl (bpy) linker with tunable 3d metal cations (Co2+, Ni2+, Cu2+, Zn2+) and chiral auxiliary ligands (R-3-chloromandelate, S-3-phenyllactate, and S-3,3-dimethyllactate) were synthesized and characterized by X-ray crystallography. Complexes with chloromandelate and dimethyllactate ligands are the first structurally characterized coordination compounds of such chiral molecules. All the compounds are based on robust chain motifs {M(bpy)}∞, decorated with chiral acid residues and other ligands. One structure represents a rare example of a triple-chained ribbon (double ladder), while five others are nearly isostructural, featuring rigid metal-organic chains, decorated by chiral pendant ligands.",

keywords = "Chain structures, Chirality, Metal-organic frameworks, Transition metals",

author = "Zavakhina, {Marina S.} and Samsonenko, {Denis G.} and Dybtsev, {Danil N.} and Fedin, {Vladimir P.}",

year = "2015",

month = mar,

doi = "10.1002/zaac.201400336",

language = "English",

volume = "641",

pages = "590--595",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "3-4",

}

RIS

TY - JOUR

T1 - Rigid 1D Coordination Polymers with Tunable Metal Cation and Chiral Pendant Moieties

AU - Zavakhina, Marina S.

AU - Samsonenko, Denis G.

AU - Dybtsev, Danil N.

AU - Fedin, Vladimir P.

PY - 2015/3

Y1 - 2015/3

N2 - A series of homochiral chain coordination polymers, based on structurally robust 4,4′-bipyridyl (bpy) linker with tunable 3d metal cations (Co2+, Ni2+, Cu2+, Zn2+) and chiral auxiliary ligands (R-3-chloromandelate, S-3-phenyllactate, and S-3,3-dimethyllactate) were synthesized and characterized by X-ray crystallography. Complexes with chloromandelate and dimethyllactate ligands are the first structurally characterized coordination compounds of such chiral molecules. All the compounds are based on robust chain motifs {M(bpy)}∞, decorated with chiral acid residues and other ligands. One structure represents a rare example of a triple-chained ribbon (double ladder), while five others are nearly isostructural, featuring rigid metal-organic chains, decorated by chiral pendant ligands.

AB - A series of homochiral chain coordination polymers, based on structurally robust 4,4′-bipyridyl (bpy) linker with tunable 3d metal cations (Co2+, Ni2+, Cu2+, Zn2+) and chiral auxiliary ligands (R-3-chloromandelate, S-3-phenyllactate, and S-3,3-dimethyllactate) were synthesized and characterized by X-ray crystallography. Complexes with chloromandelate and dimethyllactate ligands are the first structurally characterized coordination compounds of such chiral molecules. All the compounds are based on robust chain motifs {M(bpy)}∞, decorated with chiral acid residues and other ligands. One structure represents a rare example of a triple-chained ribbon (double ladder), while five others are nearly isostructural, featuring rigid metal-organic chains, decorated by chiral pendant ligands.

KW - Chain structures

KW - Chirality

KW - Metal-organic frameworks

KW - Transition metals

UR - http://www.scopus.com/inward/record.url?scp=84924859481&partnerID=8YFLogxK

U2 - 10.1002/zaac.201400336

DO - 10.1002/zaac.201400336

M3 - Article

AN - SCOPUS:84924859481

VL - 641

SP - 590

EP - 595

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 3-4

ER -

ID: 25417940