Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones. / Lukoyanov, A. N.; Romashev, N. F.; Komlyagina, V. I. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 49, № 12, 12.2023, стр. 800-806.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones
AU - Lukoyanov, A. N.
AU - Romashev, N. F.
AU - Komlyagina, V. I.
AU - Kokovkin, V. V.
AU - Cherkasov, A. V.
AU - Gushchin, A. L.
N1 - This work was supported by the Russian Science Foundation, project no. 21-13-00092. Публикация для корректировки.
PY - 2023/12
Y1 - 2023/12
N2 - The reaction of PdCl2 with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl2]2[Pd(Dpp-mian)2Cl2] (I). Complex I contains two structural units: [Pd(Dpp-mian)Cl2] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)2Cl2] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl2 with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl2] (II) (CIF file CCDC no. 2280529). Compound I is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (I)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.
AB - The reaction of PdCl2 with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl2]2[Pd(Dpp-mian)2Cl2] (I). Complex I contains two structural units: [Pd(Dpp-mian)Cl2] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)2Cl2] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl2 with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl2] (II) (CIF file CCDC no. 2280529). Compound I is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (I)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.
KW - XRD
KW - complexes
KW - cyclic voltammetry
KW - iminoacenaphthenones
KW - palladium
KW - synthesis
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180129361&origin=inward&txGid=568e9677c310a9c82dc9305e9fdea43d
UR - https://www.mendeley.com/catalogue/ef2229c0-0449-39dc-86bb-94d3417ecb46/
U2 - 10.1134/S1070328423601176
DO - 10.1134/S1070328423601176
M3 - Article
VL - 49
SP - 800
EP - 806
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 12
ER -
ID: 59545412