TY - JOUR

T1 - Properties of chromatographic columns prepared on the basis of poly(1-trimethylsilyl-1-propyne) modified with organic bases

AU - Yakovleva, Elena Y.

AU - Patrushev, Yuri V.

AU - Shundrina, Inna K.

AU - Glazneva, Tatiana S.

N1 - Properties of chromatographic columns prepared on the basis of poly(1-trimethylsilyl-1-propyne) modified with organic bases / E. Y. Yakovleva, Yu. V. Patrushev, I. K. Shundrina, T. S. Glazneva // Journal of Chromatography A. – 2024. – Vol. 1723. – P. 464914. – DOI 10.1016/j.chroma.2024.464914.

PY - 2024/5/24

Y1 - 2024/5/24

N2 - This article describes the effect of modification with organic bases such as uracil (U) and polyethyleneimine (PEI) on the adsorption and chromatographic properties of poly(1-trimethylsilyl-1-propyne) (PTMSP) used as a stationary phase (SP) in packed and capillary columns. It was shown that the sorbents prepared on the basis of diatomite Chromosorb P NAW support and successively modified with 9 wt.% PTMSP and 1 wt.% U (or PEI) (PC-U and PC-PEI samples, respectively), have a mesoporous structure. The IR spectrum shows the presence of carbonyl groups in the sorbent modified with uracil. The impregnation of the Chromosorb P NAW + (9/1) wt.% PTMSP sorbent with a polyethyleneimine solution leads to the appearance in the spectrum of bands characterizing NH stretching and bending vibrations, as well as a band at 1310 cm -1 which can be attributed to CN bond vibrations. The chromatographic properties of the studied sorbents differ significantly from the properties of the initial PTMSP. Packed columns PC-U and PC-PEI, as well as capillary columns with a polyethyleneimine-modified PTMSP layer, allow one to selectively separate mixtures of polar and non-polar compounds and structural isomers of hydrocarbons. Methanol on these columns is eluted in the form of a symmetrical peak separately from propane, propylene and other associated hydrocarbon impurities in commercial (technical, target) n-butane.

AB - This article describes the effect of modification with organic bases such as uracil (U) and polyethyleneimine (PEI) on the adsorption and chromatographic properties of poly(1-trimethylsilyl-1-propyne) (PTMSP) used as a stationary phase (SP) in packed and capillary columns. It was shown that the sorbents prepared on the basis of diatomite Chromosorb P NAW support and successively modified with 9 wt.% PTMSP and 1 wt.% U (or PEI) (PC-U and PC-PEI samples, respectively), have a mesoporous structure. The IR spectrum shows the presence of carbonyl groups in the sorbent modified with uracil. The impregnation of the Chromosorb P NAW + (9/1) wt.% PTMSP sorbent with a polyethyleneimine solution leads to the appearance in the spectrum of bands characterizing NH stretching and bending vibrations, as well as a band at 1310 cm -1 which can be attributed to CN bond vibrations. The chromatographic properties of the studied sorbents differ significantly from the properties of the initial PTMSP. Packed columns PC-U and PC-PEI, as well as capillary columns with a polyethyleneimine-modified PTMSP layer, allow one to selectively separate mixtures of polar and non-polar compounds and structural isomers of hydrocarbons. Methanol on these columns is eluted in the form of a symmetrical peak separately from propane, propylene and other associated hydrocarbon impurities in commercial (technical, target) n-butane.

KW - Organic bases

KW - Packed columns

KW - Plot columns

KW - Poly(1-trimethylsilyl-1-propyne)

KW - Stationary phase modification

KW - Polyethyleneimine/chemistry

KW - Adsorption

KW - Trimethylsilyl Compounds/chemistry

KW - Uracil/chemistry

KW - Organosilicon Compounds/chemistry

KW - Porosity

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85190727363&origin=inward&txGid=bf5a1fe91f4865163d223f3a98271559

UR - https://www.mendeley.com/catalogue/a938f5ef-52fc-35dc-831e-070bb59531b1/

UR - https://elibrary.ru/item.asp?id=67017729

U2 - 10.1016/j.chroma.2024.464914

DO - 10.1016/j.chroma.2024.464914

M3 - Article

C2 - 38640880

VL - 1723

SP - 464914

JO - Journal of Chromatography A

JF - Journal of Chromatography A

SN - 0021-9673

M1 - 464914

ER -