Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Probable metal-insulator transition in Ag4SSe. / Drebushchak, V. A.; Pal'Yanova, G. A.; Seryotkin, Yu V. и др.
в: Journal of Alloys and Compounds, Том 622, 15.02.2015, стр. 236-242.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Probable metal-insulator transition in Ag4SSe
AU - Drebushchak, V. A.
AU - Pal'Yanova, G. A.
AU - Seryotkin, Yu V.
AU - Drebushchak, T. N.
PY - 2015/2/15
Y1 - 2015/2/15
N2 - New phase transition (285 K) in lowerature monoclinic Ag4SSe was found out below the α-β transition (358 K) after the measurements with differential scanning calorimetry. The transition reveals significant hysteresis (over 30 K). X-ray powder diffraction shows that the superlattice with doubled a and b parameters of the unit cell exists below the new transition point. The signs of this new phase transition can be found in thermal and electrical conductivity of Ag4SSe published in literature. Elusive phase transition in Ag2Se shows similar properties. The new transition is likely related to the metal-insulator type transition, like K3Cu8S6.
AB - New phase transition (285 K) in lowerature monoclinic Ag4SSe was found out below the α-β transition (358 K) after the measurements with differential scanning calorimetry. The transition reveals significant hysteresis (over 30 K). X-ray powder diffraction shows that the superlattice with doubled a and b parameters of the unit cell exists below the new transition point. The signs of this new phase transition can be found in thermal and electrical conductivity of Ag4SSe published in literature. Elusive phase transition in Ag2Se shows similar properties. The new transition is likely related to the metal-insulator type transition, like K3Cu8S6.
KW - AgSSe
KW - Calorimetry X-ray diffraction
KW - DSC
KW - Metal-insulator transition
KW - Superlattice
UR - http://www.scopus.com/inward/record.url?scp=84908432146&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2014.10.065
DO - 10.1016/j.jallcom.2014.10.065
M3 - Article
AN - SCOPUS:84908432146
VL - 622
SP - 236
EP - 242
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
ER -
ID: 25754362