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Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution. / Glebov, Evgeni M.; Pozdnyakov, Ivan P.; Matveeva, Svetlana G. и др.

в: Photochemical and Photobiological Sciences, Том 16, № 2, 01.01.2017, стр. 220-227.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Glebov, EM, Pozdnyakov, IP, Matveeva, SG, Melnikov, AA, Chekalin, SV, Rogozina, MV, Yudanov, VV, Grivin, VP & Plyusnin, VF 2017, 'Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution', Photochemical and Photobiological Sciences, Том. 16, № 2, стр. 220-227. https://doi.org/10.1039/c6pp00382f

APA

Glebov, E. M., Pozdnyakov, I. P., Matveeva, S. G., Melnikov, A. A., Chekalin, S. V., Rogozina, M. V., Yudanov, V. V., Grivin, V. P., & Plyusnin, V. F. (2017). Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution. Photochemical and Photobiological Sciences, 16(2), 220-227. https://doi.org/10.1039/c6pp00382f

Vancouver

Glebov EM, Pozdnyakov IP, Matveeva SG, Melnikov AA, Chekalin SV, Rogozina MV и др. Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution. Photochemical and Photobiological Sciences. 2017 янв. 1;16(2):220-227. doi: 10.1039/c6pp00382f

Author

Glebov, Evgeni M. ; Pozdnyakov, Ivan P. ; Matveeva, Svetlana G. и др. / Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution. в: Photochemical and Photobiological Sciences. 2017 ; Том 16, № 2. стр. 220-227.

BibTeX

@article{6e7d5c03afdd4f039b6a20498e8503dd,
title = "Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution",
abstract = "The photoaquation of the OsIVCl6 2- complex was studied by means of stationary photolysis, nanosecond laser flash photolysis and ultrafast kinetic spectroscopy. The OsIVCl5(OH)2- complex was found to be the only reaction product. The quantum yield of photoaquation is rather low and wavelength-dependent. No impact of redox processes on photoaquation was revealed. The total characteristic lifetime of the process is about 80 ps. Three intermediates were recorded in the femto- and picosecond time domains and assigned to different Os(iv) species. The nature of intermediates and possible mechanisms of photoaquation are discussed.",
keywords = "Coordination Complexes/chemistry, Kinetics, Lasers, Osmium/chemistry, Oxidation-Reduction, Photolysis/radiation effects, Spectrophotometry, Ultraviolet, Water/chemistry, SPIN-CROSSOVER, METHANOL, ELECTRON-TRANSFER SPECTRA, OSCL62, IRCL62-COMPLEX, EXCITED-STATES, SPECTROSCOPY, ULTRAFAST, DYNAMICS",
author = "Glebov, {Evgeni M.} and Pozdnyakov, {Ivan P.} and Matveeva, {Svetlana G.} and Melnikov, {Alexei A.} and Chekalin, {Sergey V.} and Rogozina, {Marina V.} and Yudanov, {Vladislav V.} and Grivin, {Vjacheslav P.} and Plyusnin, {Victor F.}",
year = "2017",
month = jan,
day = "1",
doi = "10.1039/c6pp00382f",
language = "English",
volume = "16",
pages = "220--227",
journal = "Photochemical and Photobiological Sciences",
issn = "1474-905X",
publisher = "Royal Society of Chemistry",
number = "2",

}

RIS

TY - JOUR

T1 - Primary photophysical and photochemical processes for hexachloroosmate(iv) in aqueous solution

AU - Glebov, Evgeni M.

AU - Pozdnyakov, Ivan P.

AU - Matveeva, Svetlana G.

AU - Melnikov, Alexei A.

AU - Chekalin, Sergey V.

AU - Rogozina, Marina V.

AU - Yudanov, Vladislav V.

AU - Grivin, Vjacheslav P.

AU - Plyusnin, Victor F.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The photoaquation of the OsIVCl6 2- complex was studied by means of stationary photolysis, nanosecond laser flash photolysis and ultrafast kinetic spectroscopy. The OsIVCl5(OH)2- complex was found to be the only reaction product. The quantum yield of photoaquation is rather low and wavelength-dependent. No impact of redox processes on photoaquation was revealed. The total characteristic lifetime of the process is about 80 ps. Three intermediates were recorded in the femto- and picosecond time domains and assigned to different Os(iv) species. The nature of intermediates and possible mechanisms of photoaquation are discussed.

AB - The photoaquation of the OsIVCl6 2- complex was studied by means of stationary photolysis, nanosecond laser flash photolysis and ultrafast kinetic spectroscopy. The OsIVCl5(OH)2- complex was found to be the only reaction product. The quantum yield of photoaquation is rather low and wavelength-dependent. No impact of redox processes on photoaquation was revealed. The total characteristic lifetime of the process is about 80 ps. Three intermediates were recorded in the femto- and picosecond time domains and assigned to different Os(iv) species. The nature of intermediates and possible mechanisms of photoaquation are discussed.

KW - Coordination Complexes/chemistry

KW - Kinetics

KW - Lasers

KW - Osmium/chemistry

KW - Oxidation-Reduction

KW - Photolysis/radiation effects

KW - Spectrophotometry, Ultraviolet

KW - Water/chemistry

KW - SPIN-CROSSOVER

KW - METHANOL

KW - ELECTRON-TRANSFER SPECTRA

KW - OSCL62

KW - IRCL62-COMPLEX

KW - EXCITED-STATES

KW - SPECTROSCOPY

KW - ULTRAFAST

KW - DYNAMICS

UR - http://www.scopus.com/inward/record.url?scp=85012951117&partnerID=8YFLogxK

U2 - 10.1039/c6pp00382f

DO - 10.1039/c6pp00382f

M3 - Article

C2 - 28009886

AN - SCOPUS:85012951117

VL - 16

SP - 220

EP - 227

JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

SN - 1474-905X

IS - 2

ER -

ID: 10309140