Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers. / Dybtsev, Danil N.; Sapianik, Aleksandr A.; Fedin, Vladimir P.
в: Mendeleev Communications, Том 27, № 4, 01.07.2017, стр. 321-331.Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
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TY - JOUR
T1 - Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers
AU - Dybtsev, Danil N.
AU - Sapianik, Aleksandr A.
AU - Fedin, Vladimir P.
PY - 2017/7/1
Y1 - 2017/7/1
N2 - The tailored synthesis of periodic coordination structures is fundamentally important for the design of porous compounds with desired functionalities. The building block approach allows a rational and modular design of metal-organic frameworks to be accomplished from the scratch. This concept takes the advantage of the structural robustness and fixed geometry of ligands in the pre-synthesized complexes. Moreover, such a synthetic protocol can lead to otherwise unaccessible coordination structures. This review outlines the examples of the successful creation of metal-organic frameworks from discrete polynuclear complexes. We hope this work will inspire researchers in their everlasting quest for the targeted design of the materials with desired functionalities.
AB - The tailored synthesis of periodic coordination structures is fundamentally important for the design of porous compounds with desired functionalities. The building block approach allows a rational and modular design of metal-organic frameworks to be accomplished from the scratch. This concept takes the advantage of the structural robustness and fixed geometry of ligands in the pre-synthesized complexes. Moreover, such a synthetic protocol can lead to otherwise unaccessible coordination structures. This review outlines the examples of the successful creation of metal-organic frameworks from discrete polynuclear complexes. We hope this work will inspire researchers in their everlasting quest for the targeted design of the materials with desired functionalities.
KW - METAL-ORGANIC-FRAMEWORKS
KW - SOLID-STATE
KW - CARBOXYLATE FRAMEWORKS
KW - TRINUCLEAR COMPLEXES
KW - HYDROGEN STORAGE
KW - CRYSTAL-GROWTH
KW - DESIGN
KW - MOF-5
KW - ARCHITECTURES
KW - TEREPHTHALATE
UR - http://www.scopus.com/inward/record.url?scp=85026409323&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/0d13cde6-b0b1-32bf-a474-aa13aad9b68b/
U2 - 10.1016/j.mencom.2017.07.001
DO - 10.1016/j.mencom.2017.07.001
M3 - Review article
AN - SCOPUS:85026409323
VL - 27
SP - 321
EP - 331
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 4
ER -
ID: 10070562