TY - JOUR

T1 - Polyhalide-bonded metal complexes

T2 - Structural diversity in an eclectic class of compounds

AU - Adonin, Sergey A.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/7/15

Y1 - 2018/7/15

N2 - This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.

AB - This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.

KW - Halide complexes

KW - Halogen bonding

KW - Polyhalides

KW - Supramolecular interactions

KW - PHENYLTRIMETHYLAMMONIUM SALTS

KW - MOLECULAR-STRUCTURE

KW - COORDINATION-POLYMER

KW - POLYIODIDE NETWORKS

KW - TEMPERATURE IONIC LIQUID

KW - HALOGEN-HALOGEN INTERACTIONS

KW - RAY CRYSTAL-STRUCTURES

KW - CENTER-DOT 2I(2)

KW - X-RAY

KW - OXIDATIVE-ADDITION

UR - http://www.scopus.com/inward/record.url?scp=85045555163&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b6c9a1bf-a6de-327a-83f5-a09225c01245/

U2 - 10.1016/j.ccr.2018.04.010

DO - 10.1016/j.ccr.2018.04.010

M3 - Review article

AN - SCOPUS:85045555163

VL - 367

SP - 1

EP - 17

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -