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Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry. / Polyakova, E. V.; Pelipasov, O. V.

в: Spectrochimica Acta - Part B Atomic Spectroscopy, Том 173, 105988, 11.2020.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Polyakova EV, Pelipasov OV. Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry. Spectrochimica Acta - Part B Atomic Spectroscopy. 2020 нояб.;173:105988. doi: 10.1016/j.sab.2020.105988

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Polyakova, E. V. ; Pelipasov, O. V. / Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry. в: Spectrochimica Acta - Part B Atomic Spectroscopy. 2020 ; Том 173.

BibTeX

@article{6d7a394d9629406b92e3f6059b401ace,
title = "Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry",
abstract = "The effect of matrix elements with ionization potentials from 5.72 to 10.48 eV (In, Ga, Cu, Pb, Cd, Bi, Zn, P) on atom and ion excitation temperatures, magnesium ratio, plasma molecular species and analytical signals more 30 trace elements in atmospheric pressure nitrogen microwave induced plasma (Agilent 4100 AES MP) have been studied. The concentration of matrix elements was varied in the range of 0–1% w·w−1. It was shown that in the Hammer cavity, intensities of atomic and ionic lines with similar energies change in a similar way with increasing concentration of the matrix element. It was shown that, in general, the matrix effect doesn't correlate with the temperature. The Mg(II)/Mg(I) and both N2+/OH and N2+/N2 correlates with the ionization potential of the matrix element and reflect the degree of its manifestation.",
keywords = "Hammer cavity, Matrix effect, MIP-OES, Plasma molecular species, Plasma parameters, MP-AES, EASILY IONIZABLE ELEMENTS, CALCIUM, NITROGEN, MULTIENERGY CALIBRATION, INDUCTIVELY-COUPLED PLASMA, NITRIC-ACID",
author = "Polyakova, {E. V.} and Pelipasov, {O. V.}",
note = "The research was supported by the Ministry of Science and Education of the Russian Federation (V.45.1.4. Development of a set of informative methods for the chemical analysis of high-purity substances, functional materials and natural objects for analytical control of technological and environmental processes).",
year = "2020",
month = nov,
doi = "10.1016/j.sab.2020.105988",
language = "English",
volume = "173",
journal = "Spectrochimica Acta, Part B: Atomic Spectroscopy",
issn = "0584-8547",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Plasma molecular species and matrix effects in the Hummer cavity microwave induced plasma optical emission spectrometry

AU - Polyakova, E. V.

AU - Pelipasov, O. V.

N1 - The research was supported by the Ministry of Science and Education of the Russian Federation (V.45.1.4. Development of a set of informative methods for the chemical analysis of high-purity substances, functional materials and natural objects for analytical control of technological and environmental processes).

PY - 2020/11

Y1 - 2020/11

N2 - The effect of matrix elements with ionization potentials from 5.72 to 10.48 eV (In, Ga, Cu, Pb, Cd, Bi, Zn, P) on atom and ion excitation temperatures, magnesium ratio, plasma molecular species and analytical signals more 30 trace elements in atmospheric pressure nitrogen microwave induced plasma (Agilent 4100 AES MP) have been studied. The concentration of matrix elements was varied in the range of 0–1% w·w−1. It was shown that in the Hammer cavity, intensities of atomic and ionic lines with similar energies change in a similar way with increasing concentration of the matrix element. It was shown that, in general, the matrix effect doesn't correlate with the temperature. The Mg(II)/Mg(I) and both N2+/OH and N2+/N2 correlates with the ionization potential of the matrix element and reflect the degree of its manifestation.

AB - The effect of matrix elements with ionization potentials from 5.72 to 10.48 eV (In, Ga, Cu, Pb, Cd, Bi, Zn, P) on atom and ion excitation temperatures, magnesium ratio, plasma molecular species and analytical signals more 30 trace elements in atmospheric pressure nitrogen microwave induced plasma (Agilent 4100 AES MP) have been studied. The concentration of matrix elements was varied in the range of 0–1% w·w−1. It was shown that in the Hammer cavity, intensities of atomic and ionic lines with similar energies change in a similar way with increasing concentration of the matrix element. It was shown that, in general, the matrix effect doesn't correlate with the temperature. The Mg(II)/Mg(I) and both N2+/OH and N2+/N2 correlates with the ionization potential of the matrix element and reflect the degree of its manifestation.

KW - Hammer cavity

KW - Matrix effect

KW - MIP-OES

KW - Plasma molecular species

KW - Plasma parameters

KW - MP-AES

KW - EASILY IONIZABLE ELEMENTS

KW - CALCIUM

KW - NITROGEN

KW - MULTIENERGY CALIBRATION

KW - INDUCTIVELY-COUPLED PLASMA

KW - NITRIC-ACID

UR - http://www.scopus.com/inward/record.url?scp=85092606790&partnerID=8YFLogxK

U2 - 10.1016/j.sab.2020.105988

DO - 10.1016/j.sab.2020.105988

M3 - Article

AN - SCOPUS:85092606790

VL - 173

JO - Spectrochimica Acta, Part B: Atomic Spectroscopy

JF - Spectrochimica Acta, Part B: Atomic Spectroscopy

SN - 0584-8547

M1 - 105988

ER -

ID: 25674836