Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts. / Badmaev, S. D.; Akhmetov, N. O.; Sobyanin, V. A.
в: Topics in Catalysis, Том 63, № 1-2, 01.03.2020, стр. 196-202.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts
AU - Badmaev, S. D.
AU - Akhmetov, N. O.
AU - Sobyanin, V. A.
N1 - This work was supported by Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A17-117041710088-0). Publisher Copyright: © 2019, Springer Science+Business Media, LLC, part of Springer Nature. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/3/1
Y1 - 2020/3/1
N2 - Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).
AB - Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).
KW - Dimethoxymethane
KW - Noble metal catalyst
KW - Partial oxidation
KW - Pt
KW - SOFC
KW - Syngas production
KW - METHANOL
KW - HYDROGEN-RICH GAS
KW - RH
KW - DIMETHYL ETHER
KW - DECOMPOSITION
UR - http://www.scopus.com/inward/record.url?scp=85075375097&partnerID=8YFLogxK
U2 - 10.1007/s11244-019-01207-9
DO - 10.1007/s11244-019-01207-9
M3 - Article
AN - SCOPUS:85075375097
VL - 63
SP - 196
EP - 202
JO - Topics in Catalysis
JF - Topics in Catalysis
SN - 1022-5528
IS - 1-2
ER -
ID: 22403443