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Parahydrogen-induced polarization with a metal-free P-P biradicaloid. / Zhivonitko, Vladimir V.; Bresien, Jonas; Schulz, Axel и др.

в: Physical Chemistry Chemical Physics, Том 21, № 11, 13.03.2019, стр. 5890-5893.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Zhivonitko, VV, Bresien, J, Schulz, A & Koptyug, IV 2019, 'Parahydrogen-induced polarization with a metal-free P-P biradicaloid', Physical Chemistry Chemical Physics, Том. 21, № 11, стр. 5890-5893. https://doi.org/10.1039/c8cp07625a

APA

Zhivonitko, V. V., Bresien, J., Schulz, A., & Koptyug, I. V. (2019). Parahydrogen-induced polarization with a metal-free P-P biradicaloid. Physical Chemistry Chemical Physics, 21(11), 5890-5893. https://doi.org/10.1039/c8cp07625a

Vancouver

Zhivonitko VV, Bresien J, Schulz A, Koptyug IV. Parahydrogen-induced polarization with a metal-free P-P biradicaloid. Physical Chemistry Chemical Physics. 2019 март 13;21(11):5890-5893. doi: 10.1039/c8cp07625a

Author

Zhivonitko, Vladimir V. ; Bresien, Jonas ; Schulz, Axel и др. / Parahydrogen-induced polarization with a metal-free P-P biradicaloid. в: Physical Chemistry Chemical Physics. 2019 ; Том 21, № 11. стр. 5890-5893.

BibTeX

@article{38cd205a4d8b4532a00af30e8c785004,
title = "Parahydrogen-induced polarization with a metal-free P-P biradicaloid",
abstract = " Metal-free H 2 activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)] 2 , provides pronounced 1 H and 31 P hyperpolarization while activating the parahydrogen molecules. A brief analysis of the resulting NMR signals and the important kinetic parameters are presented. ",
keywords = "NUCLEAR-SPIN HYPERPOLARIZATION, STATE NMR CHARACTERIZATION, HETEROGENEOUS HYDROGENATION, FREE ACTIVATION, CATALYSIS, TWEEZERS, ENHANCE, AMMONIA, PHIP",
author = "Zhivonitko, {Vladimir V.} and Jonas Bresien and Axel Schulz and Koptyug, {Igor V.}",
note = "Publisher Copyright: {\textcopyright} 2019 the Owner Societies.",
year = "2019",
month = mar,
day = "13",
doi = "10.1039/c8cp07625a",
language = "English",
volume = "21",
pages = "5890--5893",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "11",

}

RIS

TY - JOUR

T1 - Parahydrogen-induced polarization with a metal-free P-P biradicaloid

AU - Zhivonitko, Vladimir V.

AU - Bresien, Jonas

AU - Schulz, Axel

AU - Koptyug, Igor V.

N1 - Publisher Copyright: © 2019 the Owner Societies.

PY - 2019/3/13

Y1 - 2019/3/13

N2 - Metal-free H 2 activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)] 2 , provides pronounced 1 H and 31 P hyperpolarization while activating the parahydrogen molecules. A brief analysis of the resulting NMR signals and the important kinetic parameters are presented.

AB - Metal-free H 2 activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)] 2 , provides pronounced 1 H and 31 P hyperpolarization while activating the parahydrogen molecules. A brief analysis of the resulting NMR signals and the important kinetic parameters are presented.

KW - NUCLEAR-SPIN HYPERPOLARIZATION

KW - STATE NMR CHARACTERIZATION

KW - HETEROGENEOUS HYDROGENATION

KW - FREE ACTIVATION

KW - CATALYSIS

KW - TWEEZERS

KW - ENHANCE

KW - AMMONIA

KW - PHIP

UR - http://www.scopus.com/inward/record.url?scp=85062838296&partnerID=8YFLogxK

U2 - 10.1039/c8cp07625a

DO - 10.1039/c8cp07625a

M3 - Article

C2 - 30694276

AN - SCOPUS:85062838296

VL - 21

SP - 5890

EP - 5893

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 11

ER -

ID: 18863112