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Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties. / Gukova, A. K.; Komlyagina, V. I.; Bakaev, I. V. и др.

в: Journal of Structural Chemistry, Том 66, № 4, 07.05.2025, стр. 868-876.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Vancouver

Gukova AK, Komlyagina VI, Bakaev IV, Chekhov EV, Fomenko IS, Romashev NF и др. Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties. Journal of Structural Chemistry. 2025 май 7;66(4):868-876. doi: 10.1134/S002247662504016X

Author

Gukova, A. K. ; Komlyagina, V. I. ; Bakaev, I. V. и др. / Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties. в: Journal of Structural Chemistry. 2025 ; Том 66, № 4. стр. 868-876.

BibTeX

@article{777e1ab1903f46f6b31d3c39b30c665c,
title = "Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties",
abstract = "Abstract: The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.",
keywords = "DFT calculations, XRD, acenaphthenhydrazones, complexes, cyclic voltammetry, electron absorption spectroscopy, ligands, palladium, synthesis",
author = "Gukova, {A. K.} and Komlyagina, {V. I.} and Bakaev, {I. V.} and Chekhov, {E. V.} and Fomenko, {I. S.} and Romashev, {N. F.} and Gushchin, {A. L.}",
note = "This work was funded by the Russian Science Foundation (project No. 24-73-10014). Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties / A. K. Gukova, V. I. Komlyagina, I. V. Bakaev [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 4. – P. 868-876. – DOI 10.1134/S002247662504016X.",
year = "2025",
month = may,
day = "7",
doi = "10.1134/S002247662504016X",
language = "English",
volume = "66",
pages = "868--876",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "4",

}

RIS

TY - JOUR

T1 - Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties

AU - Gukova, A. K.

AU - Komlyagina, V. I.

AU - Bakaev, I. V.

AU - Chekhov, E. V.

AU - Fomenko, I. S.

AU - Romashev, N. F.

AU - Gushchin, A. L.

N1 - This work was funded by the Russian Science Foundation (project No. 24-73-10014). Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties / A. K. Gukova, V. I. Komlyagina, I. V. Bakaev [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 4. – P. 868-876. – DOI 10.1134/S002247662504016X.

PY - 2025/5/7

Y1 - 2025/5/7

N2 - Abstract: The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.

AB - Abstract: The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.

KW - DFT calculations

KW - XRD

KW - acenaphthenhydrazones

KW - complexes

KW - cyclic voltammetry

KW - electron absorption spectroscopy

KW - ligands

KW - palladium

KW - synthesis

UR - https://www.mendeley.com/catalogue/9ccc9218-8e0a-376f-98e5-e937f0424f81/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105004480890&origin=inward&txGid=ee88ef4f9e7a18d6a47d611bd51de5f5

UR - https://elibrary.ru/item.asp?id=82272594

U2 - 10.1134/S002247662504016X

DO - 10.1134/S002247662504016X

M3 - Article

VL - 66

SP - 868

EP - 876

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 66251544