Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties. / Gukova, A. K.; Komlyagina, V. I.; Bakaev, I. V. и др.
в: Journal of Structural Chemistry, Том 66, № 4, 07.05.2025, стр. 868-876.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties
AU - Gukova, A. K.
AU - Komlyagina, V. I.
AU - Bakaev, I. V.
AU - Chekhov, E. V.
AU - Fomenko, I. S.
AU - Romashev, N. F.
AU - Gushchin, A. L.
N1 - This work was funded by the Russian Science Foundation (project No. 24-73-10014). Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties / A. K. Gukova, V. I. Komlyagina, I. V. Bakaev [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 4. – P. 868-876. – DOI 10.1134/S002247662504016X.
PY - 2025/5/7
Y1 - 2025/5/7
N2 - Abstract: The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.
AB - Abstract: The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.
KW - DFT calculations
KW - XRD
KW - acenaphthenhydrazones
KW - complexes
KW - cyclic voltammetry
KW - electron absorption spectroscopy
KW - ligands
KW - palladium
KW - synthesis
UR - https://www.mendeley.com/catalogue/9ccc9218-8e0a-376f-98e5-e937f0424f81/
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105004480890&origin=inward&txGid=ee88ef4f9e7a18d6a47d611bd51de5f5
UR - https://elibrary.ru/item.asp?id=82272594
U2 - 10.1134/S002247662504016X
DO - 10.1134/S002247662504016X
M3 - Article
VL - 66
SP - 868
EP - 876
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 4
ER -
ID: 66251544