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Overview of low-temperature heat capacity data for Zn2(C8H4O4)2·C6H12N2 and the Salam hypothesis. / Kozlova, Svetlana; Ryzhikov, Maxim; Pishchur, Denis и др.

в: Symmetry, Том 11, № 5, 657, 01.05.2019.

Результаты исследований: Научные публикации в периодических изданияхобзорная статьяРецензирование

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Kozlova S, Ryzhikov M, Pishchur D, Mirzaeva I. Overview of low-temperature heat capacity data for Zn2(C8H4O4)2·C6H12N2 and the Salam hypothesis. Symmetry. 2019 май 1;11(5):657. doi: 10.3390/sym11050657

Author

Kozlova, Svetlana ; Ryzhikov, Maxim ; Pishchur, Denis и др. / Overview of low-temperature heat capacity data for Zn2(C8H4O4)2·C6H12N2 and the Salam hypothesis. в: Symmetry. 2019 ; Том 11, № 5.

BibTeX

@article{0630db9d671a4a278b09e0f49c108246,
title = "Overview of low-temperature heat capacity data for Zn2(C8H4O4)2·C6H12N2 and the Salam hypothesis",
abstract = "The review presents the progress in the analysis of low-temperature heat capacity of the metal-organic framework Zn2(C8H4O4)2·C6H12N2 (Zn-DMOF). In Zn-DMOF, left-twisted D3(S) and right-twisted D3(R) DABCO molecules (C6H12N2) can transform into each other by tunneling to form a racemate. Termination of tunneling leads to a phase transition in the subsystem of twisted molecules. It is suggested that Zn-DMOF may be considered a model system to study the mechanisms of phase transitions belonging to the same type as hypothetical Salam phase transitions.",
keywords = "Heat capacity, Metal-organic framework, Racemate, Salam hypothesis, Triethylenediamine (DABCO) molecules, racemate, PHASE-TRANSITIONS, BEHAVIOR, heat capacity, METAL-ORGANIC FRAMEWORK, metal-organic framework, MOTION, triethylenediamine (DABCO) molecules, CHIRALITY",
author = "Svetlana Kozlova and Maxim Ryzhikov and Denis Pishchur and Irina Mirzaeva",
year = "2019",
month = may,
day = "1",
doi = "10.3390/sym11050657",
language = "English",
volume = "11",
journal = "Symmetry",
issn = "2073-8994",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "5",

}

RIS

TY - JOUR

T1 - Overview of low-temperature heat capacity data for Zn2(C8H4O4)2·C6H12N2 and the Salam hypothesis

AU - Kozlova, Svetlana

AU - Ryzhikov, Maxim

AU - Pishchur, Denis

AU - Mirzaeva, Irina

PY - 2019/5/1

Y1 - 2019/5/1

N2 - The review presents the progress in the analysis of low-temperature heat capacity of the metal-organic framework Zn2(C8H4O4)2·C6H12N2 (Zn-DMOF). In Zn-DMOF, left-twisted D3(S) and right-twisted D3(R) DABCO molecules (C6H12N2) can transform into each other by tunneling to form a racemate. Termination of tunneling leads to a phase transition in the subsystem of twisted molecules. It is suggested that Zn-DMOF may be considered a model system to study the mechanisms of phase transitions belonging to the same type as hypothetical Salam phase transitions.

AB - The review presents the progress in the analysis of low-temperature heat capacity of the metal-organic framework Zn2(C8H4O4)2·C6H12N2 (Zn-DMOF). In Zn-DMOF, left-twisted D3(S) and right-twisted D3(R) DABCO molecules (C6H12N2) can transform into each other by tunneling to form a racemate. Termination of tunneling leads to a phase transition in the subsystem of twisted molecules. It is suggested that Zn-DMOF may be considered a model system to study the mechanisms of phase transitions belonging to the same type as hypothetical Salam phase transitions.

KW - Heat capacity

KW - Metal-organic framework

KW - Racemate

KW - Salam hypothesis

KW - Triethylenediamine (DABCO) molecules

KW - racemate

KW - PHASE-TRANSITIONS

KW - BEHAVIOR

KW - heat capacity

KW - METAL-ORGANIC FRAMEWORK

KW - metal-organic framework

KW - MOTION

KW - triethylenediamine (DABCO) molecules

KW - CHIRALITY

UR - http://www.scopus.com/inward/record.url?scp=85066323865&partnerID=8YFLogxK

U2 - 10.3390/sym11050657

DO - 10.3390/sym11050657

M3 - Review article

AN - SCOPUS:85066323865

VL - 11

JO - Symmetry

JF - Symmetry

SN - 2073-8994

IS - 5

M1 - 657

ER -

ID: 20341946