Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and CuI Ions. / Moussa, Mehdi Elsayed; Welsch, Stefan; Lochner, Matthias и др.
в: European Journal of Inorganic Chemistry, Том 2018, № 23, 22.06.2018, стр. 2689-2694.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and CuI Ions
AU - Moussa, Mehdi Elsayed
AU - Welsch, Stefan
AU - Lochner, Matthias
AU - Peresypkina, Eugenia V.
AU - Virovets, Alexander V.
AU - Scheer, Manfred
PY - 2018/6/22
Y1 - 2018/6/22
N2 - A multicomponent approach of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with the ditopic organic linkers 4,4′-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of CuI salts of the anions [BF4]– and [PF6]– or the coordinating anion Br–, leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu4{Cp*Fe(µ3,η5:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[BF4]4n (4) and [Cu4{Cp*Fe(µ3,η5:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[PF6]4n (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu2Cl2{Cp*Fe(µ3,η5:1:1-P5)}(µ,η1:1-C12H10N2)]n (6) and [Cu2Br2{Cp*Fe(µ3,η5:1:1-P5)}(µ,η1:1-C10H8N2)]n (7).
AB - A multicomponent approach of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with the ditopic organic linkers 4,4′-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of CuI salts of the anions [BF4]– and [PF6]– or the coordinating anion Br–, leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu4{Cp*Fe(µ3,η5:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[BF4]4n (4) and [Cu4{Cp*Fe(µ3,η5:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[PF6]4n (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu2Cl2{Cp*Fe(µ3,η5:1:1-P5)}(µ,η1:1-C12H10N2)]n (6) and [Cu2Br2{Cp*Fe(µ3,η5:1:1-P5)}(µ,η1:1-C10H8N2)]n (7).
KW - Coordination modes
KW - Copper
KW - Ferrocene ligands
KW - Hybrid polymers
KW - Ligand effects
KW - BUILDING-BLOCKS
KW - CRYSTAL-STRUCTURES
KW - NETWORKS
KW - LIGAND COMPLEX
KW - 2D
KW - ABSTRACTION
KW - DIPHOSPHORUS COMPLEX
KW - SUPRAMOLECULE
KW - COORDINATION POLYMERS
KW - DICHLOROMETHANE
UR - http://www.scopus.com/inward/record.url?scp=85048868578&partnerID=8YFLogxK
U2 - 10.1002/ejic.201800112
DO - 10.1002/ejic.201800112
M3 - Article
C2 - 30034271
AN - SCOPUS:85048868578
VL - 2018
SP - 2689
EP - 2694
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 23
ER -
ID: 14155121