Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Only Para-Hydrogen Spectroscopy (OPSY) Revisited : In-Phase Spectra for Chemical Analysis and Imaging. / Pravdivtsev, Andrey N.; Kozinenko, Vitaly P.; Hövener, Jan Bernd.
в: Journal of Physical Chemistry A, Том 122, № 45, 15.11.2018, стр. 8948-8956.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Only Para-Hydrogen Spectroscopy (OPSY) Revisited
T2 - In-Phase Spectra for Chemical Analysis and Imaging
AU - Pravdivtsev, Andrey N.
AU - Kozinenko, Vitaly P.
AU - Hövener, Jan Bernd
PY - 2018/11/15
Y1 - 2018/11/15
N2 - We revisited only para-hydrogen spectroscopy (OPSY) for the analysis of para-hydrogen-enhanced NMR spectra at high magnetic fields. We found that the sign of the gradients and interpulse delays are pivotal for the performance of the sequence: the variant of double-quantum filter OPSY, where the second time interval is twice as long as the first one (OPSYd-12) converts the antiphase spectrum to in-phase and efficiently suppresses the background signal in a single scan better than the other variants. OPSYd-12 strongly facilitates the analysis of para-hydrogen-derived NMR spectra in homogeneous and inhomogeneous magnetic fields. Furthermore, the net magnetization produced is essential for subsequent applications such as imaging, e.g., in a reaction chamber or in vivo.
AB - We revisited only para-hydrogen spectroscopy (OPSY) for the analysis of para-hydrogen-enhanced NMR spectra at high magnetic fields. We found that the sign of the gradients and interpulse delays are pivotal for the performance of the sequence: the variant of double-quantum filter OPSY, where the second time interval is twice as long as the first one (OPSYd-12) converts the antiphase spectrum to in-phase and efficiently suppresses the background signal in a single scan better than the other variants. OPSYd-12 strongly facilitates the analysis of para-hydrogen-derived NMR spectra in homogeneous and inhomogeneous magnetic fields. Furthermore, the net magnetization produced is essential for subsequent applications such as imaging, e.g., in a reaction chamber or in vivo.
KW - PARAHYDROGEN INDUCED POLARIZATION
KW - NMR SIGNAL ENHANCEMENT
KW - SINGLET SPIN STATES
KW - PASADENA HYPERPOLARIZATION
KW - REVERSIBLE EXCHANGE
KW - COHERENT EVOLUTION
KW - ORDER TRANSFER
KW - C-13
KW - RESONANCE
KW - SABRE
UR - http://www.scopus.com/inward/record.url?scp=85055168009&partnerID=8YFLogxK
U2 - 10.1021/acs.jpca.8b07459
DO - 10.1021/acs.jpca.8b07459
M3 - Article
C2 - 30293421
AN - SCOPUS:85055168009
VL - 122
SP - 8948
EP - 8956
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
SN - 1089-5639
IS - 45
ER -
ID: 17488250