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One-dimensional polymeric polybromotellurates(IV) : Structural and theoretical insights into halogen⋯halogen contacts. / Usoltsev, Andrey N.; Adonin, Sergey A.; Novikov, Alexander S. и др.

в: CrystEngComm, Том 19, № 39, 21.10.2017, стр. 5934-5939.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Usoltsev, AN, Adonin, SA, Novikov, AS, Samsonenko, DG, Sokolov, MN & Fedin, VP 2017, 'One-dimensional polymeric polybromotellurates(IV): Structural and theoretical insights into halogen⋯halogen contacts', CrystEngComm, Том. 19, № 39, стр. 5934-5939. https://doi.org/10.1039/c7ce01487b

APA

Usoltsev, A. N., Adonin, S. A., Novikov, A. S., Samsonenko, D. G., Sokolov, M. N., & Fedin, V. P. (2017). One-dimensional polymeric polybromotellurates(IV): Structural and theoretical insights into halogen⋯halogen contacts. CrystEngComm, 19(39), 5934-5939. https://doi.org/10.1039/c7ce01487b

Vancouver

Usoltsev AN, Adonin SA, Novikov AS, Samsonenko DG, Sokolov MN, Fedin VP. One-dimensional polymeric polybromotellurates(IV): Structural and theoretical insights into halogen⋯halogen contacts. CrystEngComm. 2017 окт. 21;19(39):5934-5939. doi: 10.1039/c7ce01487b

Author

Usoltsev, Andrey N. ; Adonin, Sergey A. ; Novikov, Alexander S. и др. / One-dimensional polymeric polybromotellurates(IV) : Structural and theoretical insights into halogen⋯halogen contacts. в: CrystEngComm. 2017 ; Том 19, № 39. стр. 5934-5939.

BibTeX

@article{d986049e8b5a43b591f925ae026f8f47,
title = "One-dimensional polymeric polybromotellurates(IV): Structural and theoretical insights into halogen⋯halogen contacts",
abstract = "Reactions of TeO2 and Br2 in concentrated HBr in the presence of various organic cations resulted in the formation of one-dimensional supramolecular polymers with the structure cation2{[TeBr6](Br2)}. In the crystal structures, the Br2 units are connected to [TeBr6]2- octahedra via halogen-halogen contacts, building linear chains of two different geometries. The nature of the Br⋯Br, Br⋯Cl, and Cl⋯Cl contacts in the present and previously reported complexes of this family was investigated by theoretical methods, allowing the estimation of their energies (0.9-3.8 kcal mol-1).",
keywords = "CRYSTAL-STRUCTURE, PHENYLTRIMETHYLAMMONIUM SALTS, THERMOCHROMIC PROPERTIES, IONIC COMPOUND, CENTER-DOT, HALOGEN, BROMINE, ELECTRON, HEXACHLOROTELLURATE(IV), NONABROMOANTIMONATE(V)",
author = "Usoltsev, {Andrey N.} and Adonin, {Sergey A.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",
note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",
year = "2017",
month = oct,
day = "21",
doi = "10.1039/c7ce01487b",
language = "English",
volume = "19",
pages = "5934--5939",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "39",

}

RIS

TY - JOUR

T1 - One-dimensional polymeric polybromotellurates(IV)

T2 - Structural and theoretical insights into halogen⋯halogen contacts

AU - Usoltsev, Andrey N.

AU - Adonin, Sergey A.

AU - Novikov, Alexander S.

AU - Samsonenko, Denis G.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

N1 - Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017/10/21

Y1 - 2017/10/21

N2 - Reactions of TeO2 and Br2 in concentrated HBr in the presence of various organic cations resulted in the formation of one-dimensional supramolecular polymers with the structure cation2{[TeBr6](Br2)}. In the crystal structures, the Br2 units are connected to [TeBr6]2- octahedra via halogen-halogen contacts, building linear chains of two different geometries. The nature of the Br⋯Br, Br⋯Cl, and Cl⋯Cl contacts in the present and previously reported complexes of this family was investigated by theoretical methods, allowing the estimation of their energies (0.9-3.8 kcal mol-1).

AB - Reactions of TeO2 and Br2 in concentrated HBr in the presence of various organic cations resulted in the formation of one-dimensional supramolecular polymers with the structure cation2{[TeBr6](Br2)}. In the crystal structures, the Br2 units are connected to [TeBr6]2- octahedra via halogen-halogen contacts, building linear chains of two different geometries. The nature of the Br⋯Br, Br⋯Cl, and Cl⋯Cl contacts in the present and previously reported complexes of this family was investigated by theoretical methods, allowing the estimation of their energies (0.9-3.8 kcal mol-1).

KW - CRYSTAL-STRUCTURE

KW - PHENYLTRIMETHYLAMMONIUM SALTS

KW - THERMOCHROMIC PROPERTIES

KW - IONIC COMPOUND

KW - CENTER-DOT

KW - HALOGEN

KW - BROMINE

KW - ELECTRON

KW - HEXACHLOROTELLURATE(IV)

KW - NONABROMOANTIMONATE(V)

UR - http://www.scopus.com/inward/record.url?scp=85031048585&partnerID=8YFLogxK

U2 - 10.1039/c7ce01487b

DO - 10.1039/c7ce01487b

M3 - Article

AN - SCOPUS:85031048585

VL - 19

SP - 5934

EP - 5939

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 39

ER -

ID: 8968846