Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
One- And Two-Dimensional Iodine-Rich Iodobismuthate(III) Complexes : Structure, Optical Properties, and Features of Halogen Bonding in the Solid State. / Adonin, Sergey A.; Usoltsev, Andrey N.; Novikov, Alexander S. и др.
в: Inorganic Chemistry, Том 59, № 5, 02.03.2020, стр. 3290-3296.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - One- And Two-Dimensional Iodine-Rich Iodobismuthate(III) Complexes
T2 - Structure, Optical Properties, and Features of Halogen Bonding in the Solid State
AU - Adonin, Sergey A.
AU - Usoltsev, Andrey N.
AU - Novikov, Alexander S.
AU - Kolesov, Boris A.
AU - Fedin, Vladimir P.
AU - Sokolov, Maxim N.
PY - 2020/3/2
Y1 - 2020/3/2
N2 - Reactions of BiI3, I2, and iodide salts of two different pyridinum cations result in the formation of the novel iodine-rich iodobismuthates(III) (1,3-MePy)4{[Bi4I16](I2)} (1) and (1-MePy){[BiI4](I2)0.5) (2), where the halometalate anions are connected by diiodine linkers into one- or two-dimensional supramolecular structures. Both complexes reveal narrow optical band gaps and fairly high thermal stability, favoring their potential use in photovoltaic devices.
AB - Reactions of BiI3, I2, and iodide salts of two different pyridinum cations result in the formation of the novel iodine-rich iodobismuthates(III) (1,3-MePy)4{[Bi4I16](I2)} (1) and (1-MePy){[BiI4](I2)0.5) (2), where the halometalate anions are connected by diiodine linkers into one- or two-dimensional supramolecular structures. Both complexes reveal narrow optical band gaps and fairly high thermal stability, favoring their potential use in photovoltaic devices.
KW - PEROVSKITE SOLAR-CELLS
KW - LEAD-FREE
KW - NONCOVALENT INTERACTIONS
KW - BROMINE
KW - IODOBISMUTHATE
KW - CRYSTAL
KW - CATION
KW - PERFORMANCE
KW - COMPOUND
KW - BI(III)
UR - http://www.scopus.com/inward/record.url?scp=85079823167&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.9b03734
DO - 10.1021/acs.inorgchem.9b03734
M3 - Article
C2 - 32037811
AN - SCOPUS:85079823167
VL - 59
SP - 3290
EP - 3296
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 5
ER -
ID: 23615502