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Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands. / Laricheva, Yuliya A.; Gushchin, Artem L.; Abramov, Pavel A. и др.

в: Polyhedron, Том 154, 01.11.2018, стр. 202-208.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Laricheva, YA, Gushchin, AL, Abramov, PA & Sokolov, MN 2018, 'Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands', Polyhedron, Том. 154, стр. 202-208. https://doi.org/10.1016/j.poly.2018.07.039

APA

Laricheva, Y. A., Gushchin, A. L., Abramov, P. A., & Sokolov, M. N. (2018). Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands. Polyhedron, 154, 202-208. https://doi.org/10.1016/j.poly.2018.07.039

Vancouver

Laricheva YA, Gushchin AL, Abramov PA, Sokolov MN. Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands. Polyhedron. 2018 нояб. 1;154:202-208. doi: 10.1016/j.poly.2018.07.039

Author

Laricheva, Yuliya A. ; Gushchin, Artem L. ; Abramov, Pavel A. и др. / Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands. в: Polyhedron. 2018 ; Том 154. стр. 202-208.

BibTeX

@article{d92a907974b44c7092bfc17a5421fb4f,
title = "Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands",
abstract = "New cuboidal cluster complexes of general formula [Mo3S4(M′X)Cl3L3]0/+ (M′ = Ni0, Pd0; L = dnbpy – 4,4′-dinonyl-2,2′-bipyridine or dbbpy – 4,4′-di-tert-butyl-2,2′-bipyridine; X = tu, Cl) were synthesized by reactions of trinuclear precursors [Mo3S4Cl3L3]+ with Ni(COD)2 (COD = 1,5-cyclooctadiene) or Pd2(dba)3·CHCl3 (dba = dibenzylideneacetone) in the presence of thiourea (tu) in good yields. The complexes were characterized by elemental analysis, IR, 1H NMR and ESI-MS techniques. Crystal structures of [Mo3S4(Nitu)Cl3(dbbpy)3]Cl·tu (1a), [Mo3S4(Nitu)Cl3(dbbpy)3]Cl (1b) and [Mo3S4(Pdtu)Cl3(dbbpy)3]Cl (2) were determined by X-ray analysis. The DFT calculations of the electronic structure of [Mo3S4(Pd′X)Cl3(bpy)3]0/+ (X = Cl or tu) were carried out.",
keywords = "2,2′-bipyridine, Cubane-type clusters, Molybdenum, Nickel, Palladuim, MOLYBDENUM, NOBLE-METALS, SLATER-TYPE ORBITALS, PD, CUBOIDAL CLUSTERS, PDMO3S4 CORE, TUNGSTEN, M', 2,2 '-bipyridine, SULFIDO CLUSTERS, CATALYSTS",
author = "Laricheva, {Yuliya A.} and Gushchin, {Artem L.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",
year = "2018",
month = nov,
day = "1",
doi = "10.1016/j.poly.2018.07.039",
language = "English",
volume = "154",
pages = "202--208",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2′-bipyridine type ligands

AU - Laricheva, Yuliya A.

AU - Gushchin, Artem L.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018 Elsevier Ltd

PY - 2018/11/1

Y1 - 2018/11/1

N2 - New cuboidal cluster complexes of general formula [Mo3S4(M′X)Cl3L3]0/+ (M′ = Ni0, Pd0; L = dnbpy – 4,4′-dinonyl-2,2′-bipyridine or dbbpy – 4,4′-di-tert-butyl-2,2′-bipyridine; X = tu, Cl) were synthesized by reactions of trinuclear precursors [Mo3S4Cl3L3]+ with Ni(COD)2 (COD = 1,5-cyclooctadiene) or Pd2(dba)3·CHCl3 (dba = dibenzylideneacetone) in the presence of thiourea (tu) in good yields. The complexes were characterized by elemental analysis, IR, 1H NMR and ESI-MS techniques. Crystal structures of [Mo3S4(Nitu)Cl3(dbbpy)3]Cl·tu (1a), [Mo3S4(Nitu)Cl3(dbbpy)3]Cl (1b) and [Mo3S4(Pdtu)Cl3(dbbpy)3]Cl (2) were determined by X-ray analysis. The DFT calculations of the electronic structure of [Mo3S4(Pd′X)Cl3(bpy)3]0/+ (X = Cl or tu) were carried out.

AB - New cuboidal cluster complexes of general formula [Mo3S4(M′X)Cl3L3]0/+ (M′ = Ni0, Pd0; L = dnbpy – 4,4′-dinonyl-2,2′-bipyridine or dbbpy – 4,4′-di-tert-butyl-2,2′-bipyridine; X = tu, Cl) were synthesized by reactions of trinuclear precursors [Mo3S4Cl3L3]+ with Ni(COD)2 (COD = 1,5-cyclooctadiene) or Pd2(dba)3·CHCl3 (dba = dibenzylideneacetone) in the presence of thiourea (tu) in good yields. The complexes were characterized by elemental analysis, IR, 1H NMR and ESI-MS techniques. Crystal structures of [Mo3S4(Nitu)Cl3(dbbpy)3]Cl·tu (1a), [Mo3S4(Nitu)Cl3(dbbpy)3]Cl (1b) and [Mo3S4(Pdtu)Cl3(dbbpy)3]Cl (2) were determined by X-ray analysis. The DFT calculations of the electronic structure of [Mo3S4(Pd′X)Cl3(bpy)3]0/+ (X = Cl or tu) were carried out.

KW - 2,2′-bipyridine

KW - Cubane-type clusters

KW - Molybdenum

KW - Nickel

KW - Palladuim

KW - MOLYBDENUM

KW - NOBLE-METALS

KW - SLATER-TYPE ORBITALS

KW - PD

KW - CUBOIDAL CLUSTERS

KW - PDMO3S4 CORE

KW - TUNGSTEN

KW - M'

KW - 2,2 '-bipyridine

KW - SULFIDO CLUSTERS

KW - CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85051365793&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.07.039

DO - 10.1016/j.poly.2018.07.039

M3 - Article

AN - SCOPUS:85051365793

VL - 154

SP - 202

EP - 208

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 16063715