Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Nonequilibrium Nuclear Spin States of Ethylene during Acetylene Hydrogenation with Parahydrogen over Immobilized Iridium Complexes. / Skovpin, I. V.; Sviyazov, S. V.; Burueva, D. B. и др.
в: Doklady Physical Chemistry, Том 512, № 2, 10.2023, стр. 149-157.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Nonequilibrium Nuclear Spin States of Ethylene during Acetylene Hydrogenation with Parahydrogen over Immobilized Iridium Complexes
AU - Skovpin, I. V.
AU - Sviyazov, S. V.
AU - Burueva, D. B.
AU - Kovtunova, L. M.
AU - Nartova, A. V.
AU - Kvon, R. I.
AU - Bukhtiyarov, V. I.
AU - Koptyug, I. V.
N1 - The development of methods for the synthesis of the described catalysts, as well as their studies by XPS, was carried out with the financial support of the Russian Science Foundation (project no. 19-13-00172-P). Публикация для корректировки.
PY - 2023/10
Y1 - 2023/10
N2 - Immobilized rhodium and iridium complexes have been prepared and characterized by X-ray photoelectron spectroscopy. For the first time, hyperpolarized 13C-ethylene was detected directly in the gas phase during acetylene hydrogenation with parahydrogen over immobilized iridium complexes. The line shape of polarized 13С‑ethylene unambiguously indicates that the hydrogen addition to the triple bond of acetylene over immobilized iridium complexes proceeds stereoselectively via syn-addition. It has been shown that the selective acetylene hydrogenation with parahydrogen over immobilized iridium complexes is an efficient chemical method for enriching the nuclear spin isomers of ethylene.
AB - Immobilized rhodium and iridium complexes have been prepared and characterized by X-ray photoelectron spectroscopy. For the first time, hyperpolarized 13C-ethylene was detected directly in the gas phase during acetylene hydrogenation with parahydrogen over immobilized iridium complexes. The line shape of polarized 13С‑ethylene unambiguously indicates that the hydrogen addition to the triple bond of acetylene over immobilized iridium complexes proceeds stereoselectively via syn-addition. It has been shown that the selective acetylene hydrogenation with parahydrogen over immobilized iridium complexes is an efficient chemical method for enriching the nuclear spin isomers of ethylene.
KW - NMR
KW - XPS selective hydrogenation
KW - ethylene
KW - heterogeneous catalysis
KW - hyperpolarization
KW - immobilized complexes
KW - parahydrogen
KW - parahydrogen-induced nuclear polarization
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85179888104&origin=inward&txGid=bc1960f4e54c2d1ca19f29bb2f58991f
UR - https://www.mendeley.com/catalogue/b05e7735-6a05-3add-bf62-e9553b2b5b90/
U2 - 10.1134/S0012501623600237
DO - 10.1134/S0012501623600237
M3 - Article
VL - 512
SP - 149
EP - 157
JO - Doklady Physical Chemistry
JF - Doklady Physical Chemistry
SN - 0012-5016
IS - 2
ER -
ID: 59547987