Standard

NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8. / Freude, Dieter; Dvoyashkina, Nina; Arzumanov, Sergei S. и др.

в: Journal of Physical Chemistry C, Том 123, № 3, 24.01.2019, стр. 1904-1912.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Freude, D, Dvoyashkina, N, Arzumanov, SS, Kolokolov, DI, Stepanov, AG, Chmelik, C, Jin, H, Li, Y, Kärger, J & Haase, J 2019, 'NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8', Journal of Physical Chemistry C, Том. 123, № 3, стр. 1904-1912. https://doi.org/10.1021/acs.jpcc.8b11673

APA

Freude, D., Dvoyashkina, N., Arzumanov, S. S., Kolokolov, D. I., Stepanov, A. G., Chmelik, C., Jin, H., Li, Y., Kärger, J., & Haase, J. (2019). NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8. Journal of Physical Chemistry C, 123(3), 1904-1912. https://doi.org/10.1021/acs.jpcc.8b11673

Vancouver

Freude D, Dvoyashkina N, Arzumanov SS, Kolokolov DI, Stepanov AG, Chmelik C и др. NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8. Journal of Physical Chemistry C. 2019 янв. 24;123(3):1904-1912. doi: 10.1021/acs.jpcc.8b11673

Author

Freude, Dieter ; Dvoyashkina, Nina ; Arzumanov, Sergei S. и др. / NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8. в: Journal of Physical Chemistry C. 2019 ; Том 123, № 3. стр. 1904-1912.

BibTeX

@article{998547b1511c4e0da283dbd2e257b969,
title = "NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8",
abstract = "Within the family of metal-organic frameworks, the zeolite-imidazolate framework (ZIF) of type ZIF-8 is among the most promising materials with potential application for hydrocarbon separation, notably of alkanes and alkenes. We have applied NMR spectroscopy for exploring the interaction of representative alkane/alkene mixtures with the host framework as well as the mobility of the various components in their mixture. Deviating from, for example, the separation patterns known for MFI-based membranes, the mobility of the faster molecules (alkenes) is found to remain essentially unaffected by the presence of more slowly diffusing molecules (alkanes). In addition, 2H and 67Zn magic-angle spinning NMR contributes to the characterization of ZIF-8 in search for guest-induced changes in the lattice structure.",
keywords = "ZEOLITIC-IMIDAZOLATE FRAMEWORK, TRANSITION-STATE THEORY, FIELD GRADIENT NMR, MAS PFG NMR, SELF-DIFFUSION, DEPENDENT DIFFUSION, MOLECULAR-DYNAMICS, LIGHT-HYDROCARBONS, CRYSTAL-SIZE, ADSORPTION",
author = "Dieter Freude and Nina Dvoyashkina and Arzumanov, {Sergei S.} and Kolokolov, {Daniil I.} and Stepanov, {Alexander G.} and Christian Chmelik and Hua Jin and Yanshuo Li and J{\"o}rg K{\"a}rger and J{\"u}rgen Haase",
year = "2019",
month = jan,
day = "24",
doi = "10.1021/acs.jpcc.8b11673",
language = "English",
volume = "123",
pages = "1904--1912",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - NMR Study of the Host Structure and Guest Dynamics Investigated with Alkane/Alkene Mixtures in Metal Organic Frameworks ZIF-8

AU - Freude, Dieter

AU - Dvoyashkina, Nina

AU - Arzumanov, Sergei S.

AU - Kolokolov, Daniil I.

AU - Stepanov, Alexander G.

AU - Chmelik, Christian

AU - Jin, Hua

AU - Li, Yanshuo

AU - Kärger, Jörg

AU - Haase, Jürgen

PY - 2019/1/24

Y1 - 2019/1/24

N2 - Within the family of metal-organic frameworks, the zeolite-imidazolate framework (ZIF) of type ZIF-8 is among the most promising materials with potential application for hydrocarbon separation, notably of alkanes and alkenes. We have applied NMR spectroscopy for exploring the interaction of representative alkane/alkene mixtures with the host framework as well as the mobility of the various components in their mixture. Deviating from, for example, the separation patterns known for MFI-based membranes, the mobility of the faster molecules (alkenes) is found to remain essentially unaffected by the presence of more slowly diffusing molecules (alkanes). In addition, 2H and 67Zn magic-angle spinning NMR contributes to the characterization of ZIF-8 in search for guest-induced changes in the lattice structure.

AB - Within the family of metal-organic frameworks, the zeolite-imidazolate framework (ZIF) of type ZIF-8 is among the most promising materials with potential application for hydrocarbon separation, notably of alkanes and alkenes. We have applied NMR spectroscopy for exploring the interaction of representative alkane/alkene mixtures with the host framework as well as the mobility of the various components in their mixture. Deviating from, for example, the separation patterns known for MFI-based membranes, the mobility of the faster molecules (alkenes) is found to remain essentially unaffected by the presence of more slowly diffusing molecules (alkanes). In addition, 2H and 67Zn magic-angle spinning NMR contributes to the characterization of ZIF-8 in search for guest-induced changes in the lattice structure.

KW - ZEOLITIC-IMIDAZOLATE FRAMEWORK

KW - TRANSITION-STATE THEORY

KW - FIELD GRADIENT NMR

KW - MAS PFG NMR

KW - SELF-DIFFUSION

KW - DEPENDENT DIFFUSION

KW - MOLECULAR-DYNAMICS

KW - LIGHT-HYDROCARBONS

KW - CRYSTAL-SIZE

KW - ADSORPTION

UR - http://www.scopus.com/inward/record.url?scp=85060057776&partnerID=8YFLogxK

U2 - 10.1021/acs.jpcc.8b11673

DO - 10.1021/acs.jpcc.8b11673

M3 - Article

AN - SCOPUS:85060057776

VL - 123

SP - 1904

EP - 1912

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 3

ER -

ID: 18170118