Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
New Stannandiamines Containing Photoactive Fragments. / Demkin, A. G.; Latushko, E. P.; Savkov, B. Yu и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 51, № 6, 19.09.2025, стр. 420-429.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - New Stannandiamines Containing Photoactive Fragments
AU - Demkin, A. G.
AU - Latushko, E. P.
AU - Savkov, B. Yu
AU - Sukhikh, T. S.
AU - Konchenko, S. N.
N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation and carried out with the participation of the Shared Research Facilities of the Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. New Stannandiamines Containing Photoactive Fragments / A. G. Demkin, E. P. Latushko, B. Yu. Savkov [et al.] // Russian Journal of Coordination Chemistry. – 2025. – Vol. 51, No. 6. – P. 420-429. – DOI 10.1134/S1070328425600585.
PY - 2025/9/19
Y1 - 2025/9/19
N2 - Abstract: Reactions of dibutyltin dichloride with potassium amides KNH-pap, KNH-4pbt, and KNH-2pbt (pap = 4-(phenylazo)phenyl; 4pbt = 1,3-benzothiazol-2-yl-4-phenyl; 2pbt = 1,3-benzothiazol-2-yl-2-phenyl) were studied. It was found that KNH-pap and KNH-4pbt yield only the stannandiamines nBu2Sn(NH-pap)2 (I) and nBu2Sn(NH-4pbt)2 (II), respectively. However, the reaction with KNH-2pbt gives an inseparable mixture of the stannandiamine nBu2Sn(NH-2pbt)2 (III) and the cyclodistannadiazane [nBu2Sn(N-2pbt)]2 (IV). The molecular structures of compounds I–IV were determined by single-crystal X-ray diffraction of phases I·0.5C7H8, II·0.5THF, III, and IV (CCDC nos. 2367378 (I·0.5C7H8), 2367379 (II·0.5THF), 2367380 (III), and 2367378 (IV)).
AB - Abstract: Reactions of dibutyltin dichloride with potassium amides KNH-pap, KNH-4pbt, and KNH-2pbt (pap = 4-(phenylazo)phenyl; 4pbt = 1,3-benzothiazol-2-yl-4-phenyl; 2pbt = 1,3-benzothiazol-2-yl-2-phenyl) were studied. It was found that KNH-pap and KNH-4pbt yield only the stannandiamines nBu2Sn(NH-pap)2 (I) and nBu2Sn(NH-4pbt)2 (II), respectively. However, the reaction with KNH-2pbt gives an inseparable mixture of the stannandiamine nBu2Sn(NH-2pbt)2 (III) and the cyclodistannadiazane [nBu2Sn(N-2pbt)]2 (IV). The molecular structures of compounds I–IV were determined by single-crystal X-ray diffraction of phases I·0.5C7H8, II·0.5THF, III, and IV (CCDC nos. 2367378 (I·0.5C7H8), 2367379 (II·0.5THF), 2367380 (III), and 2367378 (IV)).
KW - X-ray diffraction analysis
KW - amides
KW - ligands
KW - synthesis
KW - tin
UR - https://www.mendeley.com/catalogue/54900133-56af-3d1b-8dd1-0222a7454f21/
UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105016759162&origin=inward
UR - https://elibrary.ru/item.asp?id=82907857
U2 - 10.1134/S1070328425600585
DO - 10.1134/S1070328425600585
M3 - Article
VL - 51
SP - 420
EP - 429
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 6
ER -
ID: 69976359